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邢艳阳,丁 华,白向飞,等. 煤及燃煤产物中稀土元素的分布赋存特征研究进展[J]. 煤炭科学技术,2024,52(3):269−282. doi: 10.12438/cst.2023-1165
引用本文: 邢艳阳,丁 华,白向飞,等. 煤及燃煤产物中稀土元素的分布赋存特征研究进展[J]. 煤炭科学技术,2024,52(3):269−282. doi: 10.12438/cst.2023-1165
XING Yanyang,DING Hua,BAI Xiangfei,et al. Research progress on the distribution and occurrence characteristics of rare earth elements in coal and coal-fired products[J]. Coal Science and Technology,2024,52(3):269−282. doi: 10.12438/cst.2023-1165
Citation: XING Yanyang,DING Hua,BAI Xiangfei,et al. Research progress on the distribution and occurrence characteristics of rare earth elements in coal and coal-fired products[J]. Coal Science and Technology,2024,52(3):269−282. doi: 10.12438/cst.2023-1165

煤及燃煤产物中稀土元素的分布赋存特征研究进展

Research progress on the distribution and occurrence characteristics of rare earth elements in coal and coal-fired products

  • 摘要: 稀土元素因其特殊的性质被广泛用于永磁、冶金、储氢材料等领域,消费量逐年递增。我国是稀土元素储量大国,至2020年我国稀土元素矿产量在世界占比逐年下降,近几年有所回升,但仍需要寻找和开发其他可作为稀土元素供应源的材料。煤作为一种有机矿产,形成过程中可富集稀土元素。深入认识煤中稀土元素含量及赋存状态对后续研究其燃烧产物中稀土元素赋存和提取回收具有重要意义。国内外学者分时代、地区、煤级研究煤中稀土元素含量,对煤及其燃烧产物中的稀土元素赋存状态研究进行总结,并初步认识到我国煤及其燃烧产物中的稀土元素分布赋存特征。目前研究表明,中国煤中的平均稀土元素含量是世界煤中的平均稀土元素含量的两倍;晚二叠世时期煤中稀土元素相对富集;煤中稀土元素主要以硅酸盐态存在。稀土元素性质稳定,经过燃烧后可在燃煤产物中明显富集,主要富集在非磁性的细飞灰颗粒中。对于煤中稀土元素含量的统计应综合考虑样品来源矿区的覆盖率、样品处理方式、微量元素测试方式等因素,以提高统计数据的代表性和准确性。综合直接观测、表征测试方法、逐级化学提取法及数理统计方法以推测得到较为可靠的赋存状态。我国煤炭消费量可观,能源供应以火力发电为主,燃煤产物产量巨大,煤中稀土元素至燃煤产物中可得到几十倍的富集,探明电厂燃煤产物中稀土元素富集分布规律,结合其提取的难易程度提出对应的回收工艺,以实现对燃煤产物资源化利用。

     

    Abstract: Rare earth elements are widely used in permanent magnet, metallurgy, hydrogen storage materials and other fields due to their special properties, and their consumption is increasing year by year. China is a big country with rare earth element reserves. By 2020, China's rare earth element mineral production in the world accounted for a decline year by year, and has rebounded in recent years, but it is necessary to find and develop other materials that can be used as a supply source of rare earth elements. Coal, as a kind of organic mineral, can enrich rare earth elements during its formation. Deeply recognizing the content and occurrence state of rare earth elements in coal is of great significance for the subsequent research on the occurrence, extraction and recovery of rare earth elements in combustion products. Scholars at home and abroad studied the content of rare earth elements in coal by era, region and coal grade, and the research on the occurrence state of rare earth elements in coal and its combustion products was summarized to clearly understand the distribution characteristics of rare earth elements in coal and its combustion products in China. Current research shows that the average rare earth element content in China's coal is twice the average rare earth element content in coal in the world. Late Permian period coal is relatively rich in rare earth elements. Rare earth elements in coal mainly exist in Portland state. The properties of rare earth elements are stable, and the coal can be enriched several times to tens of times in the combustion products after combustion, mainly in the non-magnetic fine fly ash particles. In order to improve the representativeness and accuracy of statistical data, factors such as the coverage rate of coal mining area, sample processing method and trace element testing method should be comprehensively considered in the statistics of rare earth elements content in coal. Direct observation, characterization test methods, stepwise chemical extraction methods and mathematical statistical methods were synthesized to obtain a more reliable occurrence state. China has a considerable amount of coal consumption, with the main energy supply being thermal power generation. The production of coal-fired products is huge, and rare earth elements in coal can be enriched dozens of times in coal-fired products. The distribution pattern of rare earth elements in coal-fired products of power plants is explored, and corresponding recovery processes are proposed based on the difficulty of extraction, in order to achieve the resource utilization of coal-fired products.

     

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