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气化灰渣热重与旋转锥焚烧细渣试验

Thermal gravimetric study of slag from coal slurry gasification and combustion experiment of rotary combustor

  • 摘要: 以某水煤浆气化炉灰渣作为研究对象,分析灰渣的物理特性,如密度、粒度、SEM微观形貌;分析灰渣的组分,利用热重研究温度、氧气体积分数、升温速度对细渣燃烧特性的影响以及细渣在不同恒定温度和氧气体积分数时的燃烧时间;最后在旋转锥燃烧器中进行细渣的中试燃烧试验。研究表明湿灰渣堆积密度为620~650 kg/m3,脱碳细渣为421 kg/m3,脱碳粗渣为465 kg/m3;细渣中位粒径为33.9 μm,粗渣为581 μm;细渣残碳疏松多孔,有利于燃烧。等速升温时,细渣着火温度在540~590 ℃,燃尽温度在598~722 ℃;当氧气体积分数为22%,升温速度为30 K/min时,失重峰值最大,达到‒12.3%;细渣燃烧的表观活化能在140~230 kJ/mol,随着氧气体积分数增加,表观活化能增加;恒温时,细渣燃烧时间随氧气体积分数提高显著缩短,当氧气体积分数从10%提高到16%,燃烧时间减少23.3%~29.6%;中试试验结果表明,旋转锥燃烧器可以稳定燃烧气化细渣,细渣燃烧效率>90%,细渣残碳<5%。

     

    Abstract: A coal water slurry gasifier cinder was selected as the research subject to investigate its physical properties, including density, particle size and SEM morphology. The influence of temperature, oxygen concentration and heating rate on the combustion characteristics of ash slag was examined through thermogravimetric analysis. The burnout duration of ash at various constant temperatures and oxygen concentrations was analyzed. Subsequently, an incineration test for the ash was conducted using a rotating cone burner. The findings indicate that the density of wet ash slag ranges from 620 to 650 kg/m³; decarburized fine slag has a density of 421 kg/m³ while decarburized coarse slag measures 465 kg/m³. The median particle size for dried fine slag is recorded at 33.9 μm, whereas dry coarse slag measures 581 μm. The carbon residue in fine slag exhibits a loose and porous structure conducive to combustion processes. Its ignition temperature varies between 540 and 590℃ with a burnout temperature ranging from 598 to 722 °C. At an oxygen concentration of 22% and a heating rate of 30 K/min, peak weight loss reaches ‒12.3%. The apparent activation energy for fine slag combustion spans from 140 to 230 kJ/mol and increases with rising oxygen concentrations; specifically, when oxygen levels increase from 10% to 16%, combustion time decreases by approximately 23.3% to 29.6%. Pilot test results demonstrate that the rotary combustor effectively combusts and vaporizes fine slag steadily; furthermore, the combustion efficiency exceeds over 90% with residual carbon content in fine slag remaining below 5%.

     

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