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含油污泥型煤制备及燃烧特性研究

Study on preparation and combustion characteristics of oily sludge briquette

  • 摘要: 在煤炭资源消耗量大、含油污泥处置困难且造成的环境污染严重的背景下,为实现含油污泥的资源化、清洁化利用,将煤与不同比例的含油污泥混合、压制成型,制备型煤燃料,在安全高效处置含油污泥的同时,能够综合利用煤炭资源,减少污染物的排放。以含油污泥和煤混合制备的型煤燃料为研究对象,以松弛密度、松弛比、抗破碎性、抗渗水性为物理性能指标,探究含油污泥型煤的最佳成型条件,通过热重分析法研究含油污泥型煤在不同添加比例及升温速率下的燃烧特性,并使用烟气分析仪分析燃烧烟气中主要污染物的排放特征。结果表明:当添加含油污泥20%~40%(质量分数)、成型压力20 MPa、混合原料含水率为10%时,含油污泥型煤的松弛密度增大至1 g/cm3以上,抗破碎性超过90%,型煤的物理性能变优,成型效果更佳。含油污泥的添加有效改善了型煤的着火性能、燃烧特性,当添加40%的含油污泥时,制得型煤燃料的热值为19.43 MJ/kg,稳燃特性指数最大,为3.10×10−5%/(min·℃2)。另外,升高反应温度会促使NO和SO2的生成,当反应温度在900 ℃及以下时,可以更好地控制NO和SO2的排放,同时不影响多环芳烃、重金属的排放,排放浓度低于污染物排放标准限值。含油污泥和煤的混合是实现节能减排的有效方法,含油污泥的加入,降低了型煤的着火温度、燃尽温度,改善燃烧性能的同时能够有效控制污染物的排放。

     

    Abstract: Under the background of large consumption of coal resources, difficult disposal of oily sludge and serious environmental pollution, in order to realize the resourceful and clean utilization of oily sludge, coal resources can be comprehensively utilized while disposing of oily sludge in a safe and efficient way by mixing and molding oily sludge and coal. Therefore, the coal fuel prepared by mixing oily sludge and coal was investigated, with relaxation density, relaxation ratio, crushing resistance, and water permeability resistance as the physical property indexes, to explore the optimal molding conditions of oily sludge briquette. The combustion characteristics of oily sludge briquettes under different addition ratios and heating rates were analyzed by thermogravimetric analysis, and the emission characteristics of pollutants in incineration flue gas were analyzed by flue gas analyzer. The results showed that when 20%−40% of oily sludge was added, the molding pressure was 20 MPa, and the moisture content of the mixed raw materials was 10%, the relaxation density of oily sludge briquette increased to more than 1 g/cm3, and the resistance to crushing was more than 90%. The physical properties of the coal became better, and the molding effect was better. The addition of oily sludge effectively improved the ignition performance and combustion characteristics of coal. When 40% of oily sludge was added, the calorific value of the produced coal fuel was 19.43 MJ/kg, and the stable combustion characteristic index was the largest, which was 3.10×10−5%/(min·℃2). In addition, increasing the reaction temperature can contribute to the emission of NO and SO2. When the reaction temperature is 900 ℃ and below, the emission of NO and SO2 can be better controlled without affecting the emission concentration of PAHs and heavy metals, which is lower than the limit value of pollutant emission standard. The mixing of oily sludge and coal is an effective way to realize energy saving and emission reduction. The addition of oily sludge reduces the ignition temperature of the coal, the burn-out temperature, and improves the combustion performance while effectively controlling the emission of pollutants.

     

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