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煤基固废规模化绿色低碳利用研究进展与创新路径

Research progress and innovative pathways for the large-scaled green and low-carbon utilization of coal-based solid wastes

  • 摘要: 煤炭的开采与加工为我国提供了可靠的能源保障和关键的化工原料,有力地推动了工业的快速发展和社会的进步。然而,这一过程也产生了巨量的煤基固废。煤基固废不仅占用了大量土地资源,还对环境造成了不同程度的污染,尤其是在长期堆存过程中,可能释放有害气体、重金属及其他有毒物质,威胁水源、空气和土壤安全。如何高效且规模化地利用煤基固废,成为当前实现资源循环利用、减少环境污染的关键技术挑战。通过分析煤基固废的产生、分类、特性及其环境影响,对现有煤基固废进行了重新归类,系统总结了其在矿山充填、建筑材料及生态修复等领域的成熟规模化利用模式,提出了煤基固废绿色低碳利用的创新路径。研究表明:① 煤基固废可归类为变性和原性煤基固废两大类,其中变性煤基固废具有开发胶凝材料和固碳功能材料的潜力,而原性煤基固废则具备天然砂石骨料和土壤材料的特性;② 当前,煤基固废的主要规模化利用模式包括矿山充填(如胶凝材料、膏体充填和注浆充填)、建筑材料(如水泥辅料、筑路材料和预制件)、生态修复(如坍陷区回填、荒地复垦和土壤改良)和资源提取利用(炭质组分、铝、硫和稀有元素);③ 提出了煤基固废分级分质全组分利用的新技术,通过提取高价值组分并将剩余组分用于采空区充填,实现其最大化资源利用;④ 探讨了煤基固废改性协同处置高盐废水、改性充填协同储库构筑及功能性储库协同封存危险固废的创新技术。上述研究旨在提高大宗煤基固废的资源利用效率,推动煤炭产业绿色转型,为煤炭资源的可持续发展提供新路径。

     

    Abstract: Coal mining and processing have provided China with reliable energy security and essential chemical raw materials, significantly driving industrial development and social progress. However, this process has also resulted in the production of large amounts of coal-based solid waste. These wastes not only occupy vast land resources but also cause varying degrees of environmental pollution, especially during long-term storage, when they may release harmful gases, heavy metals, and other toxic substances, posing a threat to water, air, and soil safety. Therefore, efficiently and large-scale utilization of coal-based solid waste has become a key technical challenge in achieving resource recycling and reducing environmental pollution. Based on an analysis of the generation, classification, characteristics, and environmental impacts of coal-based solid waste, this paper reclassifies existing coal-based solid waste and systematically summarizes its mature large-scale utilization models in areas such as mine backfilling, construction materials, and ecological restoration. It also proposes innovative pathways for the green and low-carbon utilization of coal-based solid waste. The study shows that: ① Coal-based solid waste can be classified into two categories: denatured and original coal-based solid waste, with denatured coal-based solid waste having the potential to develop cementing materials and carbon sequestration functions, while original coal-based solid waste possesses the characteristics of natural aggregates and soil materials; ② Currently, the main large-scale utilization models of coal-based solid waste include mine backfilling (such as cementing materials, paste backfilling, and grout backfilling), construction materials (such as cement supplementary materials, road materials, and precast components), ecological restoration (such as filling of subsidence areas, reclamation of wastelands, and soil improvement), and resource extraction and utilization (carbonaceous components, aluminium, sulfur and rare elements); ③ A new technology for graded, quality-specific, and full-component utilization of coal-based solid waste is proposed, which extracts high-value components and uses the remaining components for backfilling of mined-out areas, maximizing resource utilization; ④ Innovative technologies for modifying and co-disposing of high-salinity wastewater, modifying backfill for co-constructing storage facilities, and co-sequestering hazardous solid waste in functional storage are discussed. This research aims to improve the resource utilization efficiency of bulk coal-based solid waste, promote the green transformation of the coal industry, and provide new pathways for the sustainable development of coal resources.

     

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