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多级脉冲超声激励煤体孔隙多重分形与瓦斯解吸动力学特征

Multilevel pulse ultrasonic excitation of multifractal characteristics of coal

  • 摘要: 利用含瓦斯煤体超声波激励试验系统,开展多级脉冲超声波激励下饱水煤体瓦斯解吸试验;基于多重分形理论,结合低压CO2吸附、低温N2吸附和高压压汞试验,研究多级脉冲超声波激励下煤体微孔(<2 nm)、介孔(2~50 nm)和大孔(>50 nm)的多重分形特征及其对瓦斯解吸动力学影响规律。结果表明:与持续超声波激励煤体相比,多级脉冲超声波激励煤体各孔径段孔容和孔比表面积均有所提增大;多级脉冲超声波激励下煤体孔隙分布具有多重分形特征,微孔多重分形奇异谱谱宽∆α介于0.422 3~0.481 4,介孔谱宽∆α介于0.485 7~0.574 2,大孔谱宽∆α介于2.099 8~2.100 8;微孔和介孔在超声波激励下煤体多重分形差DminDmax发生显著变化,且随超声波多级脉冲次数增加而减小,大孔在超声波激励下多重分形差DminDmax改变不明显;相比Langmuir型、准一级动力学模型,准二级动力学模型可更为准确地表征超声波激励下煤体瓦斯解吸动力学规律,随超声波功率及多级脉冲次数增加,煤体微孔和介孔多重分形谱参数∆α整体减小,广义分形维数D、极限瓦斯解吸量Q平衡常数b和解吸速率常数k1、k2增大;多级脉冲超声波激励下煤体孔隙均匀度增大,促使极限瓦斯解吸量Q和解吸速率常数k2相对无脉冲超声波(200 W)激励增幅达105.660%和125.641%;多级脉冲超声波激活煤体孔隙多尺度改造,并显著改善煤体微孔和介孔几何形态、连通性及均匀性,影响微孔和介孔内瓦斯强吸附位点,进而促进煤体瓦斯解吸,后续可进一步探究超声波作用下煤体多尺度瓦斯解吸扩散模型构建等问题。

     

    Abstract: In order to explore the multifractal characteristics of the pore structure of coal under multistage pulse ultrasonic excitation and its impact on the desorption kinetic laws of gas, the ultrasonic excitation test system for gas-containing coal was employed to conduct the gas desorption test of water-saturated coal under multi-level pulse ultrasonic excitation. Coupled with low-pressure CO2 adsorption, low-temperature N2 adsorption, and high-pressure mercury intrusion tests, based on the multifractal theory, the multifractal characteristics of micropores (<2 nm), mesopores (2-50 nm), and macropores (>50 nm) of coal under multi-level pulse ultrasonic stimulation and their influence on the kinetics of gas desorption were studied. The results indicate that compared with the continuous ultrasonic excitation of coal, the pore volume and specific surface area of each pore diameter segment of coal under multi-level pulse ultrasonic excitation have all increased. The pore distribution of coal under multi-level pulse ultrasonic excitation exhibits multifractal characteristics. The multifractal singularity spectrum width ∆α of micropores ranges from 0.422 3 to 0.481 4, that of mesopores ranges from 0.485 7 to 0.574 2, and that of macropores ranges from 2.099 8 to 2.100 8. The multifractal difference DminDmax of micropores and mesopores in coal under ultrasonic excitation undergoes a significant change and shows a decreasing trend with the increase in the number of multi-level pulse ultrasonic waves, while the change in the multifractal difference DminDmax of macropores under ultrasonic excitation is not obvious. Compared with the Langmuir model and the pseudo-first-order kinetic model, the pseudo-second-order kinetic model can more accurately describe the kinetics of gas desorption from coal under ultrasonic excitation. With the increase in ultrasonic power and the number of multistage pulses, the multifractal spectrum parameter ∆α of micropores and mesopores of coal presents a downward trend, while the generalized fractal dimension D, the limit gas desorption amount Q, the equilibrium constant b, and the desorption rate constants k1 and k2 all increase. Under the excitation of multilevel pulse ultrasonic waves, the uniformity of coal pores is improved, which leads to the increase of the ultimate desorption amount of gas Q and the desorption rate constant k2 by 105.660% and 125.641% respectively compared with the excitation of non-pulse ultrasonic waves (200 W).Multi-level pulse ultrasonic waves activate the synergistic multi-scale transformation of coal pores and significantly enhance the geometric morphology, connectivity, and uniformity of micropores and mesopores of coal, influencing the strong adsorption sites of gas within micropores and mesopores, thereby promoting the desorption of gas in coal. Subsequently, issues such as the construction of a multi-scale gas desorption and diffusion model of coal under the action of ultrasonic waves can be further explored.

     

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