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优选L−色氨酸复配环戊烷对含煤体系瓦斯水合物生成动力学影响

Effect of preferred L-tryptophan complexed with cyclopentane on kinetics of gas hydrate generation in coal-containing systems

  • 摘要: 随着煤矿开采深度的增加,煤与瓦斯突出事故时有发生,亟需采取有效措施消除煤与瓦斯突出灾害。瓦斯水合固化技术能有效降低煤层中的瓦斯含量和压力,消除潜在突出灾害危险性。氨基酸兼具高效促进、低成本、环保和无泡沫等特点,可为深部煤层瓦斯水合固化防突技术提供参考。为此开展含煤体系中不同L−色氨酸质量分数(0.025%、0.050%、0.075%)瓦斯水合物生成动力学实验,筛选出L−色氨酸质量分数为0.075%,与环戊烷(摩尔分数5.56%)进行溶液复配,研究含煤体系中瓦斯水合物生成动力学变化。结果表明:各粒径体系中0.075%L−色氨酸的RN,30t90以及全过程生长速率均优于0.025%,0.05%L−色氨酸。0.075%L−色氨酸溶液与环戊烷5.56%溶液复配后,复配体系诱导时间均小于其他体系,对瓦斯水合诱导时间明显缩减,瓦斯水合速率分别提升89.6%、87.8%、85.0%、79.2%。通过水合物生成过程形貌分析,得出煤粒径越大,煤体内部生成水合物量呈增加趋势。各体系中,水合物生成速率呈现先增大后减小的趋势,大幅缩短了瓦斯水合进程,有望为瓦斯水合固化防突技术在深部煤层应用提供一种新的思路。

     

    Abstract: With the increasing depth of coal mining, coal and gas outburst accidents occur from time to time, making it imperative to adopt effective measures to eliminate such disasters. Gas hydrate solidification technology can effectively reduce gas content and pressure in coal seams, thereby mitigating the risk of potential outburst hazards. Amino acids, as a class of highly efficient kinetic promoters for hydrate formation, offer advantages such as low cost, environmental friendliness, and foam-free solutions, providing valuable insights for the application of gas hydrate solidification in outburst prevention in deep coal seams. In this study, kinetic experiments on gas hydrate formation in coal-containing systems were conducted with different mass fractions of L-tryptophan (0.025%, 0.05%, and 0.075%). The optimal mass fraction of L-tryptophan was identified as 0.075% and was combined with cyclopentane (CP-5.56%) to investigate the kinetics of gas hydrate formation in coal-containing systems. The results demonstrate that in systems with various particle sizes, the 0.075% L-tryptophan solution exhibited superior performance in terms of RN,30, t90, and overall growth rate compared to the 0.025% and 0.05% L-tryptophan solutions. After combining the 0.075% L-tryptophan solution with 5.56% cyclopentane, the induction time of the hybrid system was shorter than that of other systems, significantly reducing the induction time for gas hydrate formation and increasing the gas hydrate formation rate by 89.6%, 87.8%, 85.0% and 79.2%, respectively. Morphological analysis of the hydrate formation process revealed that larger coal particle sizes resulted in greater amounts of hydrate formed within the coal matrix. In all systems, the hydrate formation rate initially increased and then decreased, substantially shortening the gas hydrate formation process. This study offers a promising new approach for the application of gas hydrate solidification technology in outburst prevention in deep coal seams.

     

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