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黄赞, 孙斌, 杨青, 马施民, 邵延文, 田文广, 祁灵, 黄雷. 鸡西盆地煤储层吸附孔特征及分形表征研究[J]. 煤炭科学技术, 2021, 49(5): 218-226.
引用本文: 黄赞, 孙斌, 杨青, 马施民, 邵延文, 田文广, 祁灵, 黄雷. 鸡西盆地煤储层吸附孔特征及分形表征研究[J]. 煤炭科学技术, 2021, 49(5): 218-226.
HUANG Zan, SUN Bin, YANG Qing, MA Shiming, SHAO Yanwen, TIAN Wenguang, QI Ling, HUANG Lei. Study on characterization and fractal features of adsorption pores of coal reservoirs in Jixi Basin[J]. COAL SCIENCE AND TECHNOLOGY, 2021, 49(5): 218-226.
Citation: HUANG Zan, SUN Bin, YANG Qing, MA Shiming, SHAO Yanwen, TIAN Wenguang, QI Ling, HUANG Lei. Study on characterization and fractal features of adsorption pores of coal reservoirs in Jixi Basin[J]. COAL SCIENCE AND TECHNOLOGY, 2021, 49(5): 218-226.

鸡西盆地煤储层吸附孔特征及分形表征研究

Study on characterization and fractal features of adsorption pores of coal reservoirs in Jixi Basin

  • 摘要: 为研究有利于煤层气勘探开发的煤储层孔隙结构特征,采集8个具代表性的鸡西盆地不同矿区煤岩样品进行了工业分析和低温液氮吸附试验。基于低温液氮吸附数据,采用分形几何学原理及方法定量表征了鸡西盆地煤储层吸附孔孔隙结构特征。运用Frenkel-Halsey-Hill(FHH)模型计算了吸附孔分形维数D1(相对压力为0~0.5)和D2(相对压力为0.5~1.0),并探讨了分形维数与孔隙结构、物质组成以及煤变质程度的关系。研究结果表明:研究区煤岩样品吸附孔的孔隙形态主要包括半封闭的狭缝形孔、开放性较好的平行板状孔以及墨水瓶或细颈瓶形孔3种类型。较小相对压力阶段分形维数D1变化范围1.38~2.74,平均为2.32,较大相对压力阶段分形维数D2变化2.30~2.84,平均为2.59。其中,D1表征煤吸附孔表面粗糙程度而D2表征吸附孔结构的不规则性,D1越高,孔比表面积越大;D2越高,平均孔径越小,微孔含量越高,孔隙内部非均质性越强。不同吸附回线类型的煤样分形维数D1呈现出Ⅲ类>Ⅱ类>Ⅰ类的规律,D2则呈现出Ⅲ类>Ⅰ类>Ⅱ类的规律,D1与水分、灰分以及镜质组含量均呈多项式分布,而D2与水分及镜质组含量呈现负相关关系,与灰分关系不明显。D1和D2与镜质体反射率Ro关系均不明显。

     

    Abstract: In order to investigate coal reservoir pore structure characteristics which is favor of coalbed methane exploration and development,we collected 8 kinds of coal from different coal mine areas in Jixi Basin,based on low temperature nitrogen adsorption experiment,we used the nitrogen adsorption fractal geometry analysis method to quantitatively characterize the coal reservoir adsorptive pore structural features in Jixi Basin .The adsorptive pore fractal dimensions D1(relative pressure 0~0.5) and D2 (relative pressure 0.5~1.0) were obtained from the nitrogen adsorption isotherm using the FHH equation discussed relationship between fractal dimension and pore structure,material composition,as well as the degree of coal metamorphism. Results showed that pore morphology in the study area can be partitioned into 3 types,mainly including slit shaped pores,better openness parallel plate-like pores and ink bottle or narrow neck shaped pores. Fractal dimensions D1 was 1.38~2.74 and the average fractal dimensions D1 was 2.32; fractal dimensions D2 was 2.30~2.84 and the average fractal dimensions D2 was 2.59. D1representing the surface roughness of adsorption pores and D2 the irregularity of the pore structures. As D1 gets bigger,the pore specific surface area increases,whereas the bigger D2 gets,the smaller the average pore size becomes,the higher the micropore content is,and the larger the pore heterogeneity is. Pore fractal dimension D1 of coal samples with different adsorption and desorption curve types presents a pattern of typeⅢ>typeⅡ>typeⅠ,while D2 presents a pattern of type Ⅲ>typeⅠ>type Ⅱ. Between D1and moisture,ash yield,vitrinite content all present polynomial distribution,but between D2 and moisture content,vitrinite content present linear negative correlation,correlation with coal Ro is not apparent.

     

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