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赵世永, 郑化安, 吕淑湛, 徐婕, 邹芳. 半焦末表面改性浮选脱灰及机理研究[J]. 煤炭科学技术, 2016, (1).
引用本文: 赵世永, 郑化安, 吕淑湛, 徐婕, 邹芳. 半焦末表面改性浮选脱灰及机理研究[J]. 煤炭科学技术, 2016, (1).
Zhao Shiyong Zheng Huaan Lyu Shuzhan xuJie Zou Fang, . Study on mechanism of floatation deashing of surface modified semi coke fine[J]. COAL SCIENCE AND TECHNOLOGY, 2016, (1).
Citation: Zhao Shiyong Zheng Huaan Lyu Shuzhan xuJie Zou Fang, . Study on mechanism of floatation deashing of surface modified semi coke fine[J]. COAL SCIENCE AND TECHNOLOGY, 2016, (1).

半焦末表面改性浮选脱灰及机理研究

Study on mechanism of floatation deashing of surface modified semi coke fine

  • 摘要: 低变质煤热解后矿物质在其中富集而导致灰分升高,从而影响了半焦的后续加工利用。为此研究基于浮选脱除矿物质的基本理论,以半焦末为研究对象,在基本性质分析的基础上,采用药剂表面改性浮选分离方法,脱除半焦中的矿物质以降低其灰分。结果表明:用非离子表面活性剂改性时浮选效果最好,其次是阴离子表面活性剂,最后是阳离子表面活性剂。同时,采用扫描电镜、润湿热、红外光谱、表面电位等分析方法,进行了半焦表面改性浮选机理研究。表面活性剂与半焦颗粒表面的吸附主要存在静电吸附、氢键键合和芳环的共轭效应。

     

    Abstract: after the pyrolysis of the low metanomphic coalthe enrichment ofthe mineral would cause the ash content increased and would affect to the late processing and utiliratin ofthe senmi coke.Based on the bas c theoryof the fictaton to remove the minerals taing the semicoke as the study object and based on the analysis on the basic proertythe separation method with the reagent surace modfed ficataion was appied to remove the minerals ofthe seni coke in order to reduce theash content. The resuts showed tht when the modication made with the non- ionic suractant.the ficataton efect as the best.when th mo ficaton made with the anion surfactanth ffct would be the second and when the modification made with th catio suractant th fiect would be the last Mheanwhile the scanmning electromicroscope, wetting heat.infrared spectrum.surace potenial and other analysis methods were applied to stuay surace modification foatatio mechanism of the semi cke.The surfactant and the particle surface adsorption of the semi coke would mainly exist in conjugation eff c of h elecrostatic adsopion hyrogen bonding and aomatic ring.

     

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