软、硬煤结构特征与吸附特性研究
Study on structure characteristics and adsorption features of soft and hard coal
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摘要: 为了研究不同软、硬煤层瓦斯含量与孔隙结构的关系,以山西沁水煤田余梧矿区3号煤层为研究对象,采用等温吸附试验分析了不同软、硬煤的瓦斯吸附特性;通过低压液氮吸附试验研究了不同软、硬煤的孔隙结构特征,并从煤的微观孔隙结构角度分析了不同软、硬煤的瓦斯吸附控制机理。研究结果表明:不同软、硬煤样的瓦斯吸附能力差异明显,瓦斯吸附能力随煤体破坏程度的增加而增大;温度对不同软、硬煤瓦斯吸附能力有重要影响,在相同的吸附压力下,瓦斯吸附量与温度呈负相关,煤体瓦斯吸附能力随温度升高而减弱;从原生煤到糜棱煤,随煤体破坏程度的增加,煤孔径减小,孔比表面积增加,孔隙结构趋于复杂化。余梧矿区构造煤发育,煤中复杂孔隙结构使得煤储层含有大量瓦斯,但由于构造应力作用,软煤渗透性低,影响煤层气开发。Abstract: In order to study the relationship between the gas reserves and the pore structure in different soft and hard seams, based on No. 3 seam in Yuwu Mining Area of Shanxi Qinshui basin as the study object, an isotherm adsorption experiment was applied to analyze the gas adsorption characteristics of the different soft and hard coal. A low pressure liquid nitrogen adsorption experiment was applied to study the pore structure characteristics of the different soft and hard coal and to analyze the gas adsorption contral mechanism of different soft and hard coal from a view of the coal microscopic pore structure. The study results showed that the gas adsorptio n capacity of different soft and hard coal samples would be different obviously and the gas adsorption capacity would be increased with the seam failure degree increas ed. The temperature would have an important influence to the gas adsorption capacity of different soft and hard coal. Under the same adsorption pressure, the gas ads orption volume would be negatively correlated to the temperature and the gas adsorption capacity of the seam would be reduced with the temperature increased. From t he in-situ coal to the mylonitic coal, with the seam failure degree increased, coal pore diameter would be reduced, the specific surface area of the pore would be increa sed and the pore structure would be complicated in tendency. The tectonic coal in Yuwu Mining Area was developed, the complicated pore structure in the coal make th e coal reservoir with great gas. Due to the tectonic stress effect, the permeability of the soft coal would be low and would be affected to the coalbed methane developm ent.