不同催化剂对准东煤的催化气化特性对比研究
Contrast research on catalytic gasification characteristics of different catalysts on Zhundong Coal
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摘要: 为掌握低温750℃条件下准东煤的催化气化特性规律,采用差示扫描量热与热重分析仪,通过确定适宜的CO2气体流量、煤焦质量和颗粒直径,研究分析了准东煤在低温、微量催化剂及其不同加载方式下的催化气化特性。结果表明:低温下,准东煤在微量催化剂条件下完成催化气化过程,催化剂添加量增加,反应速率加快,催化效果更强;催化剂加载方式不同,催化效果不同,对Ca(OH)2而言,催化效果高温高压法>浸渍法>研磨法;对K2CO3而言,催化效果研磨法>高温高压法>浸渍法;相同加载方式条件下,当催化剂添加量小于1.70%(质量分数)时,Ca(OH)2催化效果优于K2CO3;当催化剂添加量大于3.20%时,Ca(OH)2催化效果弱于K2CO3,这很可能与煤中的活性位点等因素有关。Abstract: in order to understand the rule of catalytic gasication characteritics of Zhundong Cealat the low temperature of 750 ℃.based on the determination of the appropriate Co_2 gas fiow;coke mass and paricle diameterthe dfferential scanning calorimetry and thermogravimetic analyzer were use to analyze the gasifiction characteristices of Zhundong Coal with slight catalys at low temperature under diferent loading modes The experimental resuts showed that Zhundong Cal finishedgasication atlow temperature under the acion oftrace amounts of catalyst.and with the increase of catalyt,.the reaction rate was accelerated and the catalytic efiectwas stronge:. The dfferent catalyst loading modes caused difrent cata ytc effectforcalctum hydroxide catalyticefiect rom strong to wealk as foll ws.igh temperatue and high pressure method was the best.imersion method was worse ,grinding nethod was the worst: fo potash grinding methd was the best igh temperature andhigh pessure metod was worse inmersion meliod was the worst.wih the same catalystloading mode, when the catalyst mass fraction wasless than 1.70%,calciumhydroxide was betea than potash, whie potash vas beter than calctum hydroxide when the catalyt mass racion was less than 3.20%.it was probably related to such factors as the active sites of coal.