风量对煤低温氧化中CO产出影响的试验研究
Experiment study on airflow affected to generation of CO with low temperature oxidation of coal
-
摘要: 为了研究风量对煤低温氧化自燃过程的影响,采用程序升温的方法将煤温控制在恒温条件下,通过逐渐减小风量的手段,比较了CO绝对产生量随煤温和风量的变化规律,确定了不同煤温时的当量风量,并根据CO增长率变化确定了煤自燃的临界温度。通过理论分析和试验研究,基于CO绝对产生量和风量,推导了煤活化能的表达式,得出了煤温、CO绝对产生量、风量和活化能四者之间的关系式。研究结果表明,CO绝对产生量随风量的增大而增大,超过当量风量后,CO绝对产生量基本保持不变;煤温越高,煤自燃所需的当量风量越大。该研究对深入探索煤自燃机理和指导现场煤自燃防治具有重要的意义。Abstract: in order to study the airfiow affected to the low temperature oxidized spontaneous combustion process of coal a programmed temperature rising method was applied to the coal temperature control under the condition of the constant temperature.with the means to steadily reduce the airflow,the variation law of absolute yield of C0 with coal temperature and aifiow was compared,and the equivalent airfiow at different coal temperature was determined.According to the variation of C0 increased rat ,the crtical temperature of the coal spontaneous combustion was determined.Wwith the theoretcal analysis and experiment study,based on the absolute yield of CO,in combination with the mine airfilow;,the expresson formula of the coal activated energy was derived and the relational expression between the coal temperature, absolute yield of CO aifiow andactivated energy was obtained.The study results showed that the absolute yield of CO would be increased with the mine airflow increased. When the equivalent airflow was exceeded,the absolute yield of CO would be kept in constant basically.The higher the coal temperature was,the greaterthe equivalent airfiow required by coal spontaneous combustion.The study would have important significances to deep probe the oal spontaneots combustion mechanism and to the site guidance of the coal spontaneous combustion prevention and control.