低温热-碱解改性对污泥与煤共成浆特性的影响
Effects of low temperature thermal-alkaline modification on co-slurrying performances of sludge and coal
-
摘要: 为提高污泥利用效率,采用低温热-碱解方法对污泥进行预处理,利用改性后的污泥与煤掺混制备浆体燃料,研究了低温热-碱解方法对改性前后污泥水煤浆表观黏度、流变性、剪切迟滞性的影响。结果表明,低温热-碱解方法能有效降低污泥水煤浆的黏度,当剪切速率为100 s-1时,原始污泥水煤浆的表观黏度为1 667 m Pa·s,污泥经90℃-Ca(OH)2改性1、4、24 h后,浆体的表观黏度分别降至1 027.6、698.0、455.8 m Pa·s,污泥经90℃-NaOH改性1、4、24 h后,浆体的表观黏度分别降至674.8、436.3、385.8 m Pa·s。同时,浆体的流变性逐步由假塑性趋近于牛顿流体,浆体的剪切迟滞特性减弱,原始污泥水煤浆的迟滞环面积(Hla)为2 078.0 Pa/s。在90℃-Ca(OH)2和90℃-NaOH的条件下处理1 h后,污泥水煤浆的迟滞环面积分别降为774.5、664.5 Pa/s。可见,低温热-碱解方法能有效提高污泥水煤浆的成浆性,改善污泥水煤浆浆体流变特性。Abstract: In order to improve the utilization efficiency of sludge, the low temperature thermal-alkaline (LTTA) method was used to pretreat the sludge. The effects sI udge before and after modification with LTTA method on apparent viscosity of coal-sludge slurry (CSS) , rheological behavior and hysteresis loop area were studied in t he paper.The results showed that apparent viscosity of CSS was reduced effectively by LTTA method.When the shear rate was 100 s-1, apparent viscosity of raw CSS was 1 667 m Pa.s, after the sludge was modified by 90 °C-Ca (OH) 2for 1 h, 4 h and 24 h, the apparent viscosity of CSS decreased to 1 027.6, 698.0, 455.8 m Pa.s res pectively.While it decreased to 674.8, 436.3, 385.8 m Pa's after the sludge was modified by 90 °C-NaOH for 1 h, 4 h and 24 h respectively.At the same time, the rheolog ical behavior of the CSS was gradually transformed from pseudoplastic to Newtonian flow, and the shearing hysteresis of the CSS decreased, the hysteresis loop area of raw CSS was 2 078.0 Pa/s.Wheareas, the hysteresis loop area of raw CSS decreased to 774.5 Pa/s and 664.5 Pa/s after the sludge was modified by 90 °C-Ca (OH) _2, 90 °C-Na OH respectively for 1 h.The above results identified the LTTA method could efficiently improved slurrying ability and the rheological properties of CSS.