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褐煤基活性焦的制备及脱硝应用

Preparation and Denitration Application of Lignite Base Activated Coke

  • 摘要: 针对褐煤低热值、高灰高水含量、低附加值的特点,采用高温水蒸气活化试验制备了褐煤基活性焦。试验得出最佳活化工艺条件为:活化温度850℃、水蒸气通入量1.0 kg/(kg.h)、活化时间2h,此时活性焦的碘吸附值达到500 mg/g以上,烧失率为34%,在相同活化条件下,脱灰褐煤活性焦比原褐煤活性焦具有更高的碘吸附值。活性焦经3种不同质量分数10%、20%、30%硝酸铜溶液浸渍、煅烧后,制备的选择性催化还原法(SCR)脱硝催化剂在20 min内具有较高的脱硝率,活性焦脱硝率均能达到80%以上,符合工业化要求。

     

    Abstract: According to the features of low calorific value, high ash and high moisture contents and low additional value of the lignite, a high temperature steam acti vated experiment was applied to prepare the lignite base activated coke.An optimal activated technical condition obtained from the experiment was activated temperatur e of 850 °C, steam flow quantity of 1.0 kg/ (kg-h) and activated time of 2 h.Under this condition, an iodine adsorption value of the activated coke was over 500 mg/g, the ignition lost rate was 34% and under the same activated condition, the activated coke of the de-ash lignite would have a higher idine adsorption value than the activate d coke of the raw lignite .After the immersion in an copper nitrate solution with three different quantity fraction of 10%, 20% and 30% and calcinations for the activated C oke, the prepared SCR denitration catalyst would have a high denitration rate within 20 min and the denitration rate of the activated coke all could be over 80% and cou Id meet the industrial requirements.

     

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