| Citation: |
XING Yanyang，DING Hua，BAI Xiangfei，et al. Research progress on the distribution and occurrence characteristics of rare earth elements in coal and coal-fired products[J]. Coal Science and Technology，2024，52（3）：269−282. DOI: 10.12438/cst.2023-1165
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Rare earth elements are widely used in permanent magnet, metallurgy, hydrogen storage materials and other fields due to their special properties, and their consumption is increasing year by year. China is a big country with rare earth element reserves. By 2020, China's rare earth element mineral production in the world accounted for a decline year by year, and has rebounded in recent years, but it is necessary to find and develop other materials that can be used as a supply source of rare earth elements. Coal, as a kind of organic mineral, can enrich rare earth elements during its formation. Deeply recognizing the content and occurrence state of rare earth elements in coal is of great significance for the subsequent research on the occurrence, extraction and recovery of rare earth elements in combustion products. Scholars at home and abroad studied the content of rare earth elements in coal by era, region and coal grade, and the research on the occurrence state of rare earth elements in coal and its combustion products was summarized to clearly understand the distribution characteristics of rare earth elements in coal and its combustion products in China. Current research shows that the average rare earth element content in China's coal is twice the average rare earth element content in coal in the world. Late Permian period coal is relatively rich in rare earth elements. Rare earth elements in coal mainly exist in Portland state. The properties of rare earth elements are stable, and the coal can be enriched several times to tens of times in the combustion products after combustion, mainly in the non-magnetic fine fly ash particles. In order to improve the representativeness and accuracy of statistical data, factors such as the coverage rate of coal mining area, sample processing method and trace element testing method should be comprehensively considered in the statistics of rare earth elements content in coal. Direct observation, characterization test methods, stepwise chemical extraction methods and mathematical statistical methods were synthesized to obtain a more reliable occurrence state. China has a considerable amount of coal consumption, with the main energy supply being thermal power generation. The production of coal-fired products is huge, and rare earth elements in coal can be enriched dozens of times in coal-fired products. The distribution pattern of rare earth elements in coal-fired products of power plants is explored, and corresponding recovery processes are proposed based on the difficulty of extraction, in order to achieve the resource utilization of coal-fired products.
| [1] |
洪广言. 稀土化学导论[M]. 北京:科学出版社,2014.
|
| [2] |
赵志根,唐修义. 中国煤中的稀土元素[J]. 中国煤田地质,2002(S1):71−75.
ZHAO Zhigen,TANG Xiuyi. Rare-earth elements in coal of China[J]. Coal Geology of China,2002(S1):71−75.
|
| [3] |
代 涛,高天明,文博杰. 元素视角下的中国稀土供需格局及平衡利用策略[J]. 中国科学院院刊,2022,37(11):1586−1594.
DAI Tao,GAO Tianming,WEN Bojie. China’s rare earth supply and demand patte and balanced utilization strategy from perspective of elements[J]. Bulletin of Chinese Academy of Sciences,2022,37(11):1586−1594.
|
| [4] |
张双全. 煤化学[M]. 江苏:中国矿业大学出版社,2019.
|
| [5] |
SEREDIN V V,FINKELMAN R B. Metalliferous coals:A review of the main genetic and geochemical types[J]. International Journal of Coal Geology,2008,76(4):253−289. doi: 10.1016/j.coal.2008.07.016
|
| [6] |
倪嘉缵,洪广言. 中国科学院稀土研究五十年[M]. 北京:科学出版社,2005.
|
| [7] |
DAI S F,FINKELMAN R B. Coal as a promising source of critical elements:Progress and future prospects[J]. International Journal of Coal Geology,2018,186:155−164. doi: 10.1016/j.coal.2017.06.005
|
| [8] |
SEREDIN V V,DAI S. Coal deposits as potential alternative sources for lanthanides and yttrium[J]. International Journal of Coal Geology,2012,94:67−93. doi: 10.1016/j.coal.2011.11.001
|
| [9] |
GAUSTAD G, WILLIAMS E, LEADER A. Rare earth metals from secondary sources: Review of potential supply from waste and byproducts[J]. Resources, Conservation and Recycling, 2021, 167:105213.
|
| [10] |
ERNEST J M Report on rare earth elements from coal and coal byproducts[EB/OL]. United States Department of Energy,2017-1/2023-8-6.
|
| [11] |
曹雅丽. 消费结构优化 电力供应凸显绿色低碳[N]. 中国工业报,2022-02-16(T0B).
|
| [12] |
姚多喜,支霞臣,王 馨. 煤及其燃烧产物飞灰和底灰中稀土元素地球化学特征及集散规律[J]. 地球化学,2003,32(5):491−500.
YAO Duoxi,ZHI Xiachen,WANG Xin. Geochemical feature and laws of concentration and dispersion of rare earth elements between coals and their fly and bottom ashes[J]. Geochimica,2003,32(5):491−500.
|
| [13] |
吴国强,汪 涛,张永生,等. 燃煤电厂煤及其燃烧产物中稀土元素富集规律研究[J]. 中国电机工程学报,2020,40(6):1963−1972.
WU Guoqiang,WANG Tao,ZHANG Yongsheng,et al. Study on the enrichment of rare earth elements between coals and their by-products at coal-fired power plants[J]. Proceedings of the CSEE,2020,40(6):1963−1972.
|
| [14] |
唐修义,黄文辉. 中国煤中微量元素[M]. 北京:商务印书馆,2004.
|
| [15] |
赵志根,唐修义,李宝芳. 淮北煤田煤的稀土元素地球化学[J]. 地球化学,2000,29(6):578−583.
ZHAO Zhigen,TANG Xiuyi,LI Baofang. Geochemistry of rare earth elements of coal in Huaibei Coalfield[J]. Journal of Earth Science,2000,29(6):578−583.
|
| [16] |
任德贻,赵峰华,代世峰,等. 煤的微量元素地球化学[M]. 北京:科学出版社,2006.
|
| [17] |
白向飞. 中国煤中微量元素分布赋存特征及其迁移规律试验研究[D]. 北京:煤炭科学研究总院,2003.
BAI Xiangfei. The distributions,modes of occurrence and volatility of trace elements in coals of China[D]. Beijing:China Coal Research Institute,2003.
|
| [18] |
白向飞,李文华,陈亚飞,等. 中国煤中微量元素分布基本特征[J]. 煤质技术,2007,14(1):1−4.
BAI Xiangfei,LI Wenhua,CHEN Yafei,et al. The general distributions of trace elements in Chinese coals[J]. Coal Quality Technology,2007,14(1):1−4.
|
| [19] |
代世峰,任德贻,李 丹,等. 贵州大方煤田主采煤层的矿物学异常及其对元素地球化学的影响[J]. 地质学报,2006,80(4):589−597,617.
DAI Shifeng,REN Deyi,LI Dan,et al. Mineralogical Anomalies and Their Influences on Elemental Geochemistry of the Main Workable Coal Beds from the Dafang Coalfield,Guizhou,China[J]. Acta Geologica Sinica,2006,80(4):589−597,617.
|
| [20] |
DAI S,REN D,CHOU C L,et al. Geochemistry of trace elements in Chinese coals:A review of abundances,genetic types,impacts on human health,and industrial utilization[J/OL]. International Journal of Coal Geology,2012,94:3−21.
|
| [21] |
ZHANG W,REZAEE M,BHAGAVATULA A,et al. A review of the occurrence and promising recovery methods of rare earth elements from coal and coal by-products[J]. International Journal of Coal Preparation and Utilization,2015,35(6):295−330. doi: 10.1080/19392699.2015.1033097
|
| [22] |
FINKELMAN R B. Trace and minor elements in coal[M]. Organic geochemistry:principles and applications. Boston,MA:Springer US,1993:593−607.
|
| [23] |
ARBUZOV S I,CHEKRYZHOV I Y,FINKELMAN R B,et al. Comments on the geochemistry of rare-earth elements (La,Ce,Sm,Eu,Tb,Yb,Lu) with examples from coals of north Asia (Siberia,Russian far East,North China,Mongolia,and Kazakhstan)[J]. International Journal of Coal Geology,2019,206:106−120. doi: 10.1016/j.coal.2018.10.013
|
| [24] |
KETRIS M P,YUDOVICH Y E. Estimations of Clarkes for Carbonaceous biolithes:World averages for trace element contents in black shales and coals[J]. International Journal of Coal Geology,2009,78(2):135−148. doi: 10.1016/j.coal.2009.01.002
|
| [25] |
陈柯婷. 西南地区煤中稀土元素的地球化学对比研究[D]. 淮南:安徽理工大学,2017.
CHEN Keting. Geochemistry of rare earth elements in the coals from southwestern China[D]. Huainan:Anhui University of Science and Technolog,2017.
|
| [26] |
熊树斌,李杨浩,瞿 亮,等. 云南临沧大田河锗煤矿床稀土元素地球化学特征[J]. 矿物学报,2018,38(3):313−320.
XIONG Shubin,LI Yanghao,QU Liang,et al. Geochemical characteristics of rare earth elements in Ge-bearing coals from Datianhe Coal Mine,Lincang County,Yunnan Province,China[J]. Acta Mine Ralogica Sinica,2018,38(3):313−320.
|
| [27] |
马小敏. 黄县盆地古近系煤中元素地球化学特征及其沉积环境指示意义[J]. 科学技术与工程,2019,19(24):46−55. doi: 10.3969/j.issn.1671-1815.2019.24.007
MA Xiaomin. Geochemistry characteristics and sedimentary environment indicating significances of elements in paleogene coal from Huangxian Basin[J]. Science Technology and Engineering,2019,19(24):46−55. doi: 10.3969/j.issn.1671-1815.2019.24.007
|
| [28] |
孔洪亮,曾荣树,庄新国,等. 辽宁省北票煤田煤中稀土元素地球化学特征[J]. 地质科技情报,2002,21(2):75−79.
KONG Hongliang,ZENG Rongshu,ZHUANG Xinguo,et al. Geochemistry of rare earth elements of coal in beipiao coalfield[J]. Geological Science and Technology Information,2002,21(2):75−79.
|
| [29] |
杨 磊,刘池洋,李洪英. 陈家山矿煤中微量元素和稀土元素地球化学特征[J]. 煤田地质与勘探,2008,36(2):10−14.
YANG Lei,LIU Chiyang,LI Hongying. Geochemistry of trace elements and rare earth elements of coal in Chenjiashan coal mine[J]. Coal Geology & Exploration,2008,36(2):10−14.
|
| [30] |
肖 林,张佳为,周建飞,等. 青海石灰沟矿区克鲁克组煤中稀土元素地球化学特征[J]. 煤炭学报,2018,43(S2):505−512.
XIAO Lin,ZHANG Jiawei,ZHOU Jianfei,et al. Geochemistry characteristics of rare earth elements in the Keluke Formation coal from Shihuihou Area,Qinghai[J]. Journal of China Coal Society,2018,43(S2):505−512.
|
| [31] |
霍 婷,刘世明,祁文强,等. 青海木里煤田聚乎更矿区煤中稀土元素地球化学特征及其对成煤环境的指示[J]. 地质通报,2020,39(7):995−1005.
HUO Ting,LIU Shiming,QI Wenqiang,et al. Geochemistry characteristics and indicative significance of rare earth elements in coal from Juhugeng coal district the Muli coalfield in Qinghai Province[J]. Geological Bulletin of China,2020,39( 7):995−1005.
|
| [32] |
曹吉阳,姚多喜,胡永发. 攀枝花大宝顶煤矿18号煤层稀土元素地球化学特征[J]. 安徽理工大学学报(自然科学版),2016,36(2):11−15.
CAO Jiyang,YAO Duoxi,HU Yongfa. Geochemistry of rare earth elements of 18# coal seam in Dabaoding Mine from Panzhihua[J]. Journal of Anhui University of Science and Technology( Natural Science),2016,36(2):11−15.
|
| [33] |
张江义,帅 琴,胡圣虹,等. 贵州西南煤区数个煤样的稀土元素地球化学特征[J]. 稀土,2010,31(4):81−84.
ZHANG Jiangyi,SHUAI Qin,HU Shenghong,et al. Geochemistry of rare earth elements of several coal samples in southestern Guizhou[J]. Chinese Rare Earths,2010,31(4):81−84.
|
| [34] |
吴艳艳,秦 勇,易同生. 贵州凯里梁山组高硫煤中稀土元素的富集及其地质成因[J]. 地质学报,2010,84(2):280−285. doi: 10.1111/j.1755-6724.2010.00086.x
WU Yanyan,QIN Yong,YI Tongsheng. Enrichment of rare earth elements in high sulfur coal of Liangshan formation from Kaili,Guizhou,China and geological origin[J]. Acta Geologica Sinica,2010,84(2):280−285. doi: 10.1111/j.1755-6724.2010.00086.x
|
| [35] |
徐良才,黄立衡,汪成钵. 洪塘矿区二叠系乐平组官山段煤及泥岩稀土元素特征[J]. 能源技术与管理,2016,41(S1):25−29.
|
| [36] |
胡小娟,夏小进,黄 懿,等. 洪塘煤矿煤中微量和稀土元素的地球化学特征[J]. 江西煤炭科技,2019,26(1):11−14.
HU Xiaojuan,XIA Xiaojin,HUANG Yi,et al. Geochemistry of trace elements and rare earth elements of coal in Hongtang coal mine of Jiangxi Province[J]. Jiangxi Coal Science & Technology,2019,26(1):11−14.
|
| [37] |
张卫国,杨建业,石 媛. 广西合山超高有机硫煤中稀土元素特征[J]. 稀土,2019,40(2):49−56.
ZHANG Weiguo,YANG Jianye,SHI Yuan. Characteristics of Rare Earth Elements in Super High Organic Sulfur Coal in Guangxi[J]. Chinese rare earth,2019,40(2):49−56.
|
| [38] |
朱士飞,曹 泊,王 佟,等. 广西上林县万福矿区煤中稀土元素地球化学特征[J]. 中国煤炭地质,2020,32(9):64−69.
ZHU Shifei,CAO Bo,WANG Tong,et al. Geochemical Features of Coal REE in Wanfu Coalmine Area,Shanglin County,Guangxi[J]. Coal Geology of China,2020,32(9):64−69.
|
| [39] |
杨林健,聂 坤. 贵州正安春雷煤矿煤的地球化学特征分析[J]. 西部探矿工程,2020,32(10):173−176,180.
|
| [40] |
黄文辉,杨 起,汤达祯,等. 华北晚古生代煤的稀土元素地球化学特征[J]. 地质学报,1999,73(4):360−369.
HUANG Wenhui,YANG Qi,TANG Dazhen,et al. Geochemistry of rare earth elements in lake paleozoic coals in the north China[J]. Acta Geologica Sinica,1999,73(4):360−369.
|
| [41] |
杜美霞,庄新国. 华南地区晚二叠世煤的稀土元素特征[J]. 地质科技情报,2006,25(2):52−56.
DU Meixia,ZHUANG Xinguo. Analysis on the Characters of Rare-Earth Element in the Late Permi an Coal fro m South China[J]. Geological Science and Technology Information,2006,25(2):52−56.
|
| [42] |
姜尧发,王西勃,赵 蕾. 大屯矿区太原组煤中稀土元素的赋存特征[J]. 煤炭科学技术,2006,34(1):73−75.
JIANG Yaofa,WANG Xibo,ZHAO Lei. Distribution characteristics of rare-earth element in coal of Taiyuan Group in Datun Mining Area[J]. Coal Science and technology. 2006,34(1):73−75.
|
| [43] |
邹建华,刘 东,田和明,等. 内蒙古阿刀亥矿晚古生代煤的微量元素和稀土元素地球化学特征[J]. 煤炭学报,2013,38(6):1012−1018.
ZOU Jianhua,LIU Dong,TIAN Heming,et al. Geochemistry of trace and rare earth elements in the Late Paleozoic Coal from Adaohai Mine,Inner Mongolia[J]. Journal of China Coal Society,2013,38(6):1012−1018.
|
| [44] |
刘 贝,黄文辉,敖卫华,等. 沁水盆地晚古生代煤中稀土元素地球化学特征[J]. 煤炭学报,2015,40(12):2916−2926.
LIU Bei,HUANG Wenhui,AO Weihua,et al. Geochemistry characteristics of rare earth elements in the late Paleozoic coal from Qinshui Basin[J]. Journal of China Coal Society,2015,40(12):2916−2926.
|
| [45] |
秦国红,邓丽君,刘 亢,等. 鄂尔多斯盆地西缘煤中稀土元素特征[J]. 煤田地质与勘探,2016,44(6):8−14.
QIN Guohong,DENG Lijun,LIU Kang,et al. Characteristic of rare earth elements in coal in western margin of Ordos basin[J]. Coal Geology & Exploration,2016,44(6):8−14.
|
| [46] |
林龙斌. 河东煤田北部主采煤中稀土元素地球化学特征[J]. 中国煤炭地质,2018,30(11):18−23.
LIN Longbing. REE Geochemical Features of Main Mineable Coal Seams in Northern Hedong Coalfield[J]. Coal Geology of China,2018,30(11):18−23.
|
| [47] |
刘大锐,高桂梅,池君洲,等. 准格尔煤田黑岱沟露天矿煤中稀土及微量元素的分配规律[J]. 地质学报,2018,92(11):2368−2375.
LIU Darui,GAO Guimei,CHI Junzhou,et al. Distribution rule of rare earth and trace elements in the Heidaigou Openpit Coal Mine in the Junggar Coal Field[J]. Acta Geologica Sinica,2018,92(11):2368−2375.
|
| [48] |
魏迎春,华芳辉,何文博,等. 峰峰矿区2号煤中微量元素富集特征差异性研究[J]. 煤炭学报,2020,45(4):1473−1487.
WEI Yingchun,HUA Fanghui,HE Wenbo,et al. Difference of trace elements characteristics of No. 2 coal in Fengfeng mining area[J]. Journal of China Coal Society,2020,45(4):1473−1487.
|
| [49] |
刘蔚阳,樊景森,王金喜,等. 宁武煤田煤中稀土元素地球化学特征研究[J]. 煤炭科学技术,2020,48(4):237−245.
LIU Yuyang,FAN Jingsen,WANG Jinxi,et al. Study on geochemical characteristics of rare earth elements from coal in Ningwu Coalfield[J]. Coal Science and Technology,2020,48(4):237−245.
|
| [50] |
HUANG Shaoqing,NING Shuzheng,ZHANG Jianqiang,et al. REE characteristics of the coal in the Erlian Basin,Inner Mongolia,China,and its economic value[J]. China Geology,2021,4(2):256−265.
|
| [51] |
袁铎恩,边家辉,刘紫璇,等. 华北板块南缘早二叠世煤中微量元素赋存特征及主控机制[J]. 地质科技通报,2023,42(5):138−149.
YUAN Duoen,BIAN Jiahui,LIU Zixuan,et al. Occurrence characteristics and main control mechanism of trace elements in Early Permian coal on the southern margin of North China Plate[J]. Bulletin of Geological Science and Technology,2023,42(5):138−149.
|
| [52] |
DAI S,GRAHAM I T,WARD C R. A review of anomalous rare earth elements and yttrium in coal[J]. International Journal of Coal Geology,2016,159:82−95. doi: 10.1016/j.coal.2016.04.005
|
| [53] |
宁树正,吴国强,邓小利,等. 中国煤中金属元素矿产资源[M]. 北京:科学出版社,2019.
|
| [54] |
吴 盾,孙若愚,刘桂建. 淮南朱集井田二叠纪煤中稀土元素地球化学特征及其地质解释[J]. 地质学报,2013,87(8):1158−1166. doi: 10.3969/j.issn.0001-5717.2013.08.010
WU Dun,SUN Ruoyu,LIU Guijian. Characterization of REE geochemistry of the Permian Coals from the ZhujiCoal Mine,Huainan Coalfield and Its Geological Implication[J]. Acta Geologica Sinica,2013,87(8):1158−1166. doi: 10.3969/j.issn.0001-5717.2013.08.010
|
| [55] |
曹 泊,朱士飞,秦云虎,等. 煤中稀土元素研究现状及展望[J]. 煤炭科学技术,2022,50(4):181−194.
CAO Bo,ZHU Shifei,QIN Yunhu,et al. Research status and prospect of rare earth elements in coal[J]. Coal Science and Technology,2022,50(4):181−194.
|
| [56] |
吴朝东,徐友灵,郭召杰,等. 新疆焉耆盆地侏罗系煤层地球化学特征和古环境意义[J]. 自然科学进展,2006,16(2):199−206.
|
| [57] |
代世峰,任德贻,邵龙义,等. 黔西晚二叠世煤地球化学性质变异及特殊组构的火山灰成因[J]. 地球化学,2003,32(3):239−247.
DAI Shifeng,REN Deyi,SHAO Longyi,et al. Variation of coal geochemistry and special textures of Late Permian coalsin the western Guizhou Province and their volcanic origin[J]. Geochimica,2003,32(3):239−247.
|
| [58] |
宁树正,黄少青,朱士飞,等. 中国煤中金属元素成矿区带[J]. 科学通报,2019,64(24):2501−2513.
NING Shuzheng,HUANG Shaoqing,ZHU Shifei,et al. Mineralization zoning of coal-metal deposits in China. Chinese Science Bulletin,2019,64(24):2501−2513.
|
| [59] |
董国文,徐 芃,姚多喜,等. 云、贵、川地区不同变质程度煤中稀土元素含量研究[J]. 三明学院学报,2007,24(2):175−179.
DONG Guowen,XU Peng,YAO Duoxi,et al. Geochemistry of ree in different ranks of Yunnan,Guizhou and Chongqing Coal[J]. Journal of Sanming University,2007,24(2):175−179.
|
| [60] |
杨建业. 镧系元素地球化学效应方程参数之科学意义初探:以山西晚古生代太原组8号煤层不同煤级的煤为例[J]. 煤炭学报,2019,44(7):2197−2205.
YANG Jianye. Regression equation of geochemical effect of lanthanide and preliminary study on scientific significance of its parameters:an example of different types from No. 8 coal seam,Shanxi Province,China[J]. Journal of China Coal Society,2019,44(7):2197−2205.
|
| [61] |
李大华,唐跃刚,陈 坤,等. 重庆煤中稀土元素的地球化学特征研究[J]. 中国矿业大学学报,2005,34(3):312−317. doi: 10.3321/j.issn:1000-1964.2005.03.011
LI Dahua,TANG Yuegang,CHEN Kun,et al. Research on geochemistry of rare earth elements in coals from Chongqing,China[J]. Journal of China University of Mining & Technology,2005,34(3):312−317. doi: 10.3321/j.issn:1000-1964.2005.03.011
|
| [62] |
FINKELMAN R B. The origin,occurrence,and distribution of the inorganic constituents in low-rank coals[C]//Proceedings of the Basic Coal Science Workshop. US Department of Energy,Houston,TX. 1982:69−90.
|
| [63] |
DAI S,FINKELMAN R B,FRENCH D,et al. Modes of occurrence of elements in coal:A critical evaluation[J]. Earth-Science Reviews,2021,222:103815. doi: 10.1016/j.earscirev.2021.103815
|
| [64] |
LIN R,BANK T L,ROTH E A,et al. Organic and inorganic associations of rare earth elements in central Appalachian coal[J]. International Journal of Coal Geology,2017,179:295−301. doi: 10.1016/j.coal.2017.07.002
|
| [65] |
代世峰,任德贻,李生盛. 煤及顶板中稀土元素赋存状态及逐级化学提取[J]. 中国矿业大学学报,2002,31(5):12−16.
DAI Shifeng,REN Deyi,LI Shengsheng. Occurrence and sequential chemical extraction of rare earth element in coals and seam roofs[J]. Journal of China University of Mining & Technology,2002,31(5):12−16.
|
| [66] |
刘东娜,周安朝,常泽光. 大同煤田 8 号原煤及风化煤中常量元素和稀土元素地球化学特征[J]. 煤炭学报,2015,40(2):422−430.
LIU Dongna,ZHOU Anchao,CHANG Zeguang. Geochemistry characteristics of major and rare earth elements in No. 8 raw and weathered coal from Taiyuan Formation of Datong coalfield[J]. Journal of China Coal Society,2015,40(2):422−430.
|
| [67] |
杨建业. 煤中稀土元素几个奇特的地球化学现象—以渭北中级煤为例[J]. 煤炭学报,2014,39(S2):476−483.
YANG Jianye. Several special geochemical phenomena of rare earth elements in coal:A case study of middle rank coal in Weibei[J]. Journal of China Coal Society,2014,39(S2):476−483.
|
| [68] |
杨瑞林,白 燕. 应用能谱-扫描电镜和X射线衍射技术研究原煤伴生矿物中稀土和放射性元素赋存形式[J]. 岩矿测试,2019,38(4):382−393.
YANG Ruilin BAI Yan. The occurrence of rare earth and radioactive elements in the associated minerals with raw coal by EDX-SEM and XRD[J]. Rock and Mineral Analysis,2019,38(4):382−393.
|
| [69] |
ESKENAZY G M. Aspects of the geochemistry of rare earth elements in coal:an experimental approach[J]. International Journal of Coal Geology,1999,38(3−4):285−295. doi: 10.1016/S0166-5162(98)00027-5
|
| [70] |
WANG W,QIN Y,SANG S,et al. Geochemistry of rare earth elements in a marine influenced coal and its organic solvent extracts from the Antaibao mining district,Shanxi,China[J]. International Journal of Coal Geology,2008,76(4):309−317. doi: 10.1016/j.coal.2008.08.012
|
| [71] |
ARBUZOV S I,MASLOV S G,FINKELMAN R B,et al. Modes of occurrence of rare earth elements in peat from western Iberia[J]. Journal of Geochemical Exploration,2018,184:40−48. doi: 10.1016/j.gexplo.2017.10.012
|
| [72] |
FINKELMAN R B,PALMER C A,WANG P. Quantification of the modes of occurrence of 42 elements in coal[J]. International Journal of Coal Geology,2018,185:138−160. doi: 10.1016/j.coal.2017.09.005
|
| [73] |
HOWER J C,GROPPO J G,JOSHI P,et al. Distribution of lanthanides,yttrium,and scandium in the pilot-scale beneficiation of fly ashes derived from eastern Kentucky coals[J]. Minerals,2020,10(2):105. doi: 10.3390/min10020105
|
| [74] |
HONAKER R Q,ZHANG W,WERNER J,et al. Enhancement of a process flowsheet for recovering and concentrating critical materials from bituminous coal sources[J]. Mining Metallurgy & Exploration,2020,37(1):3−20.
|
| [75] |
刘桂建,彭子成,杨萍玥,等. 煤中微量元素在燃烧过程中的变化[J]. 燃料化学学报,2001,29(2):119−123.
LIU Guijian,PENG Zicheng,YANG Pingyue,et al. Changes of trace elements in coal during combustion[J]. Journal of Fuel Chemistry and Technology,2001,29(2):119−123.
|
| [76] |
ZHANG W,NOBLE A,YANG X,et al. A Comprehensive review of rare earth elements recovery from coal-related materials[J]. Minerals,2020,10(5):451. doi: 10.3390/min10050451
|
| [77] |
HOWER J C,QIAN D,BRIOT N J,et al. Nano-scale rare earth distribution in fly ash derived from the combustion of the fire clay coal,kentucky[J]. Minerals,2019,9(4):206. doi: 10.3390/min9040206
|
| [78] |
HOWER J C,CANTANDO E,EBLE C F,et al. Characterization of stoker ash from the combustion of high-lanthanide coal at a kentucky bourbon distillery[J]. International Journal of Coal Geology,2019,213:103260. doi: 10.1016/j.coal.2019.103260
|
| [79] |
HOWER J C,GROPPO J G. Rare earth-bearing particles in fly ash carbons:examples from the combustion of eastern kentucky coals[J]. Energy Geoscience,2021,2(2):90−98. doi: 10.1016/j.engeos.2020.09.003
|
| [80] |
MARDON S M,HOWER J C. Impact of coal properties on coal combustion by-product quality:Examples from a Kentucky power plant[J]. International Journal of Coal Geology,2004,59(3/4):153−169.
|
| [81] |
付 彪,姚 洪,罗光前,等. 燃煤电厂稀土元素的迁移转化与提取技术[J]. 洁净煤技术,2022,28(10):145−159.
FU Biao,YAO Hong,LUO Guangqian,et al. Partitioning behavior and extraction technologies of rare earth elements in coal-fired power plants[J]. Clean Coal Technology,2022,28( 10):145−159.
|
| [82] |
WU G,SHI N,WANG T,et al. Enrichment and occurrence form of rare earth elements during coal and coal gangue combustion[J]. Environmental Science and Pollution Research,2022,29(29):44709−44722. doi: 10.1007/s11356-022-18852-5
|
| [83] |
LI Z,LI X,ZHANG L,et al. Partitioning of rare earth elements and yttrium (REY) in five coal-fired power plants in Guizhou,Southwest China[J]. Journal of Rare Earths,2020,38(11):1257−1264. doi: 10.1016/j.jre.2019.12.013
|
| [84] |
HU Y,MA J,WANG J,et al. Differentiation of rare earth elements in coal combustion products from the handan power plant,Hebei Province,China[J]. Sustainability,2023,15(4):3420. doi: 10.3390/su15043420
|
| [85] |
WU L,MA L,HUANG G,et al. Distribution and speciation of rare earth elements in coal fly ash from the Qianxi Power Plant,Guizhou Province,Southwest China[J]. Minerals,2022,12(9):1089. doi: 10.3390/min12091089
|
| [86] |
XU F,QIN S,LI S,et al. Distribution,occurrence mode,and extraction potential of critical elements in coal ashes of the Chongqing Power Plant[J]. Journal of Cleaner Production,2022,342:130910. doi: 10.1016/j.jclepro.2022.130910
|
| [87] |
潘金禾. 粉煤灰中稀土元素赋存机制及富集提取研究[D]. 徐州:中国矿业大学,2021.
PAN Jinhe. Study on the enrichment,extraction and mechanism of occurrence of rare earth elements in coal fly ash[D]. Xuzhou:China University of Mining and Technology,2021.
|
| [88] |
SHAO P,HOU H,WANG W,et al. Geochemistry and mineralogy of fly ash from the high-alumina coal,Datong Coalfield,Shanxi,China[J]. Ore Geology Reviews,2023,158:105476. doi: 10.1016/j.oregeorev.2023.105476
|
| [89] |
LI C,ZHOU C,LI W,et al. Enrichment of critical elements from coal fly ash by the combination of physical separations[J]. Fuel,2023,336:127156. doi: 10.1016/j.fuel.2022.127156
|
| [90] |
DAI S F,ZHAO L,PENG S P,etal. Abundances and distribution of minerals and elements in high-alumina coal fly ash from the Jungar Power Plant,Inner Mongolia,China[J]. International Journal of Coal Geology,2010,81(4):320−332. doi: 10.1016/j.coal.2009.03.005
|
| [91] |
BLISSETT R S,SMALLEY N,ROWSON N A. An investigation into six coal fly ashes from the United Kingdom and Poland to evaluate rare earth element content[J]. Fuel,2014,119:236−239. doi: 10.1016/j.fuel.2013.11.053
|
| [92] |
吴国强,汪 涛,王家伟,等. 煤和煤矸石及其燃烧产物中稀土元素赋存形态研究[J]. 燃料化学学报,2020,48(12):1498−1505. doi: 10.1016/S1872-5813(20)30094-3
WU Guoqiang WANG Tao WANG Jiawei,et al. Occurrence forms of rare earth elements in coal and coal gangue and their combustion products[J]. Journal of Fuel Chemistry and Technology,2020,48(12):1498−1505. doi: 10.1016/S1872-5813(20)30094-3
|
| [93] |
秦身钧,徐 飞,崔 莉,等. 煤型战略关键微量元素的地球化学特征及资源化利用[J]. 煤炭科学技术,2022,50(3):1−38.
QIN Shenjun,XU Fei,CUI Li,et al. Geochemistry characteristics and resource utilization of strategically critical trace elements from coal-related resources[J]. Coal Science and Technology,2022,50(3):1−38.
|
| [94] |
侯霖莉, 吴 松, 易建洲, 等. 基于机器学习的绿泥石微量元素判别矿床类型[J/OL]. 地球科学: 1−24.[2028-08-10].http://kns.cnki.net/kcms/detail/42.1874.p.20230912.1324.002.html.
HOU Linli, WU Song, YI Jianzhou, et al. Discriminating deposit types using chlorite trace elements based on machine learning[J/OL]. Earth Science: 1−24.[2028-08-10].http://kns.cnki.net/kcms/detail/42.1874.p.20230912.1324.002.html.
|
| [95] |
牟力言,刘春湘,陈 敏,等. 基于机器学习识别中微量元素与我国七大片区产地稻米镉、砷的富集规律[J]. 农业环境科学学报,2023,42(10):2165−2174.
MOU Liyan,LIU Chunxiang,CHEN Min,et al. Enrichment patterns of cadmium and arsenic in rice from seven major regions in China based on machine learning recognition of minor and trace elements[J]. Journal of Agro-Environment Science,2023,42(10):2165−2174.
|
| [96] |
王祖林,韩 硕,康俊杰,等. 基于双向深度学习的电站锅炉SCR脱硝系统入口NOx浓度预测[J]. 自动化与仪表,2021,36(1):82−87.
WANG Zulin,HAN Shuo,KANG Junjie,et al. Pridiction of NOx concentration at the inlet of SCR denitration system of utility boiler based on bidirectional deep learning[J]. Automation & Instrumentation,2021,36(1):82−87.
|
| [97] |
邵良杉,毕圣昊,王彦彬,等. 基于ISSA-ELM的煤与瓦斯突出危险等级预测[J]. 中国安全生产科学技术,2023,19(9):76−82.
SHAO Liangshan,BI Shenghao,WANG Yanbin,et al. Prediction of coal and gas outburst risk level based on ISSA-ELM[J]. Journal of Safety Science and Technology,2023,19(9):76−82.
|
| [98] |
洪 瑾,甘成势,刘 洁. 基于机器学习的洋岛玄武岩主量元素预测稀土元素[J]. 地学前缘,2019,26(4):45−54.
HONG Jin,GAN Chenshi,LIU Jie. Prediction of REEs in OlB by major elements based on machine learning[J]. Earth Science Frontiers,2019,26(4):45−54.
|
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