HU Guangqing，WU Dun，WEI Chao，et al. Distribution, occurrence characteristics and geological origin of typical hazardous elements in low-medium ash coal of Huainan coalfield[J]. Coal Science and Technology，2023，51（5）：161−173
. DOI: 10.13199/j.cnki.cst.2021-1033| Citation: |
HU Guangqing，WU Dun，WEI Chao，et al. Distribution, occurrence characteristics and geological origin of typical hazardous elements in low-medium ash coal of Huainan coalfield[J]. Coal Science and Technology，2023，51（5）：161−173 . DOI: 10.13199/j.cnki.cst.2021-1033
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With the continuous development, processing and utilization of coal resources in our province, the existence of typical harmful elements in coal is bound to have a negative impact on the efficient and clean utilization of coal resources. Based on the mass data analysis of typical hazardous elements in coal of Huainan coalfield, taking the main coal seams (No.13-1, No.11-2, No.8, No.6, No.4 and No.1) as the research objects, the occurrence characteristics and geological genesis of typical hazardous elements were comprehensively analyzed by the means of ICP-MS, AFS, stepwise chemical extraction and cluster analysis. The results were as follows: ① Typical hazardous elements Cr, Co, Se and Pb in coal of Huainan coalfield are “lightly enriched”, Hg is “highly enriched” and other elements are in “normal range”; ② The high value area of As element content in Huainan coalfield was mainly located in the west of coalfield; the high value region of Hg element was located in the east of coalfield, followed by the west; the remaining eight elements (Cr, Mn, Co, Ni, Se, Cd, Sb and Pb) were all higher in coal of Panji mining area of Huainan coalfield (especially near Pansan coal mine). The late magmatic hydrothermal process in Panji-Zhuji region may be the main reason for the relative enrichment of hazardous elements such as Cr, Mn, Co, Ni, Se, Cd, Sb and Pb. ③ There were many ion-exchange States in the occurrence state of Hg, and the inorganic components brought by magmatic hydrothermal action may have little influence on the enrichment degree of Hg element. The magmatic hydrothermal intrusion in the late diagenesis period had no obvious influence on As, and the low content of As in coal may be related to the low content of As in coal-forming plants.
| [1] |
杨 杰, 叶小榕. 安徽省污染排放空间分布特征分析[J]. 荆楚理工学院学报, 2017, 32(4): 61−64.
YANG Jie, YE Xiaorong. Analysis on spatial distribution characteristics of pollution emission in Anhui Province[J]. Journal of Jingchu Institute of Technology 2017, 32 (4): 61−64.
|
| [2] |
W Minami, XU Zhenghe, K Heejoon. Mercury removal characteristics during thermal upgrading of fractionated alberta subbituminous coal[J]. Energy Fuels, 2007, 21: 3607−3611.
|
| [3] |
XU Wenqing,WANG Hairui,ZHU Tingyu. Mercury removal from coal combustion flue gas by modified fly ash[J]. Journal of Environmental Sciences,2013,25(2):393−398.
|
| [4] |
李 涛. 高山大气汞污染特征、化学转化及传输规律研究一以泰山和大帽山为例[D]. 济南: 山东大学, 2018.
LI Tao. Study on characteristics, chemical transformation and transport of atmospheric mercury in high mountains-a case study of Mount Tai and Damao Mountain [D]. Jinan: Shandong University, 2018.
|
| [5] |
SFO De Vallejuelo ,A Gredilla,K da Boit,et al. Nanominerals and potentially hazardous elements from coal cleaning rejects of abandoned mines: Environmental impact and risk assessment[J]. Chemosphere,2017,169:725−733.
|
| [6] |
A Gredilla,SFO De Vallejuelo,L Gomez-Nubla,et al. Are children playgrounds safe play areas? Inorganic analysis and lead isotope ratios for contamination assessment in recreational (Brazilian) parks[J]. Environmental Science and Pollution Research,2017,24:24333−24345.
|
| [7] |
LIU Guijian, ZHENG Liugeng, NS Duzgoren-Aydin, et al. Health effects of arsenic, fluorine, and selenium from indoor burning of Chinese coal [J]. Reviews of Environmental Contamination and Toxicology, 2007, 189: 89-106.
|
| [8] |
RUHL L,VENGOSH A,DWYER GS,et al. Survey of the potential environmental and health impacts in the immediate aftermath of the coal ash spill in Kingston, Tennessee[J]. Environ. Sci. Techno,2009,43(63):26−33.
|
| [9] |
CHEN Jian,LIU Guijian,JIANG Mengmeng,et al. Geochemistry of environmentally sensitive trace elements in Permian coals from the Huainan coalfield, Anhui, China[J]. International Journal of Coal Geology,2011,88(1):41−54.
|
| [10] |
DAI Shifeng,REN Deyi,CHOU Chenlini,et al. Geochemistry of trace elements in Chinese coals: A review of abundances, genetic types, impacts on human health, and industrial utilization[J]. International Journal of Coal Geology,2012,94:3−21.
|
| [11] |
靳新娣, 朱和平. 岩石中43种元素的高分辨等离子质谱测定[J]. 分析化学, 2000, 28(5): 563−567.
JIN Xindi, ZHU Heping. Determination of 43 elements in rocks by high resolution plasma mass spectrometry [J]. Analytical Chemistry, 2000, 28 (5): 563−567.
|
| [12] |
YANG C Q, ZANG S S, WU N, et al. Easibility study on content determination of mercury and arsenic in high organic anthracite by microwave digestion-hydride generation-atomic fluorescence spectrometry and mass spectrometry [J]. Rock and Mineral Analysis, 2016, 35(5): 481−487.
|
| [13] |
DAI Shifeng,LUO Yangbing,VV Sersdin,et al. Revisiting the late Permian coal from the Huayingshan, Sicuan, southwestern China: Erichment and occurrence modes of minerals and trace elements[J]. International Journal of Coal Geology,2014,122:110−128. doi: 10.1016/j.coal.2013.12.016
|
| [14] |
HU Guangqing, LIU Guijian, WU Dun, et al. Geochemical behavior of hazardous volatile elements in coals with difffferent geological origin during Combustion[J]. Fuel 2018, 233: 361−376.
|
| [15] |
CLARKE LB, SLOSS LL. Trace elements-Emissions from Coal Combustion and Gasification [J]. IEACR/49, IEA Coal Reasearch 1992, 111.
|
| [16] |
RB Finkelman. Modes of occurrence of environmentally-sensitive trace elements of coal. In Swaine D J, Goodarzi(eds). Environmental Aspects of Trace Elements of Coal [J]. Dordrecht: Kluwer Academic Publishers, 1995, 24−50.
|
| [17] |
DJ Swaine. Why trace elements are important [J]. Fuel Processing Technology, 2000, 65−66: 21−33.
|
| [18] |
赵峰华. 煤中有害微量元素分布赋存机制及燃煤产物淋滤实验研究[D]. 北京: 中国矿业大学(北京), 1997.
ZHAO Fenghua. Experimental study on distribution and occurrence mechanism of hazardous trace elements in coal and leaching of coal products[D]. Beijing: China University of Mining and Technology−Beijing, 1997.
|
| [19] |
苗 林, 刘桂建, 吴 盾, 等. 淮南煤田潘三井田西部岩浆岩侵入年代确定与意义[J]. 中国煤炭地质, 2012, 24(11): 4−6.
MIAO Lin, LIU Guijian, WU Dun, et al. Determination and significance of magmatic intrusion age in western Pansan coal mine, Huainan coalfield[J]. Coal geology of China, 2012, 24(11): 4−6.
|
| [20] |
A Tessier, PGC Campbell, M Blsson. Sequential extraction procedure for the speciation particulate trace metals [J]. Anal Chem 1979, 51: 844-851.
|
| [21] |
任德贻, 赵峰华, 代世峰, 等. 煤的微量元素地球化学[M]. 北京: 科学出版社, 2006.
REN Deyi, ZHAO Fenghua, DAI Shifeng, et al. Trace element geochemistry of coal [M]. Beijing: Science Press, 2006.
|
| [22] |
叶道敏. 陆相含煤岩系中煤的还原性及其形成条件——以珲春板石19-3煤层为例[J]. 煤田地质与勘探, 1990(5): 71−73.
YE Daoming. Reduction and formation conditions of coal in continental coal-bearing strata-taking Hunchun Banshi NO. 19-3 coal seam as an Example [J]. Coalfield Geology and Exploration, 1990(5): 71−73.
|
| [23] |
兰昌益. 两淮煤田石炭二叠纪含煤岩系沉积特征及沉积环境[J]. 淮南矿业学院学报, 1989(3): 9−20.
LAN Changyi. Sedimentary characteristics and sedimentary environment of Permo-Carboniferous coal-bearing strata in H nan Coalfield[J]. Journal of Huainan Institute of Mining and Technology, 1989(3): 9−20.
|
| [24] |
黄文辉,杨 起,汤达祯,等. 潘集煤矿二叠纪主采煤层中微量元素亲和性研究[J]. 地学前缘,2000(S2):263−270.
HUANG Wenhui,YANG Qi,TANG Dazheng,et al. Study on compatibility of trace elements in permian main coal seam of Panji coal mine[J]. Earth Science Frontiers,2000(S2):263−270.
|
| [25] |
陈 健, 陈 萍, 刘文中. 淮南矿区煤中12种微量元素的赋存状态及环境效应[J]. 煤田地质与勘探, 2009, 37(6): 47−52.
CHEN Jian, CHEN Ping, LIU Wenzhong. Modes of occurrence and environmental effects of 12 trace elements in coal of Huainan coalfield [J]. Coalfield Geology and Exploration, 2009, 37 (6): 47−52.
|
| [26] |
CHEN Jian. Study on the response of coal geochemistry in Huainan Coalfield to magma intrusion [D]. Hefei: China University of Science and Technology 2013.
|
| [27] |
童柳华, 严家平, 唐修义. 淮南煤中微量元素及分布特征[J]. 矿业安全环保, 2004, 31: 94−97.
TONG Liuhua, YAN Jiaping, TANG Xiuyi. Tracee elements and distribution characteristics in Huainan coalfield[J]. Mining Safety and Environmental Protection, 2004, 31: 94−97.
|
| [28] |
赵志根, 唐修义, 李宝芳. 淮南矿区煤的稀土元素地球化学[J]. 沉积学报, 2000, 18(3): 453−459.
ZHAO Zhigen, TANG Xiuyi, LI Baofang. Rare earth element geochemistry of coal in Huainan mining area[J]. Journal of Sedimentary Sciences, 2000, 18 (3): 453−459.
|
| [29] |
杨 梅. 淮南煤田(以朱集矿为例)侵入岩和煤中稀土元素地球化学特征[D]. 合肥: 中国科学技术大学, 2012.
YANG Mei. Geochemical characteristics of rare earth elements in intrusive rocks and coal in Huainan coalfield (taking zhuji mine as an example) [D]. Hefei: China University of Science and Technology, 2012.
|
| [30] |
刘文中, 朱东军, 孔维辉, 等. 淮南矿区11煤的微量元素洁净程度评价[J]. 现代矿业, 2009, 479(3): 112−114.
LIU Wenzhong, ZHU Dongjun, KONG Weihui, et al. Evaluation of trace element cleanliness in NO. 11 coalseam of Huainan coalfield[J]. Modern Mining, 2009, 479 (3): 112−114.
|
| [31] |
陈 健. 淮南煤田煤地球化学对岩浆侵入的响应研究[D]. 合肥: 中国科学技术大学, 2013.
CHEN Jian. Study on the response of coal geochemistry in Huainan coalfield to magma intrusion[D] . Hefei: China University of Science and Technology, 2013.
|
| [32] |
孔维辉. 淮南煤燃烧过程中环境意义微量元素迁移性的实验研究[D]. 淮南: 安徽理工大学, 2007.
KONG Weihui. Experimental study on migration of trace elements of environmental significance in combustion process of Huainan coalfield[D]. Huainan: Anhui University of Technology, 2007.
|
| [33] |
吴江平. 淮南煤田东部煤中微量元素及其环境意义研究[D]. 淮南: 安徽理工大学, 2006.
WU Jiangping. Study on trace elements in coal from eastern Huainan coalfield and their environmental significance [D]. Huainan: Anhui University of Technology, 2006.
|
| [34] |
平文文. 淮南潘集深部煤层微量元素分布特征及其地质意义[D]. 淮南: 安徽理工大学, 2016.
PING Wenwen. Distribution characteristics and geological significance of trace elements in deep coal seam of Panji, Huainan coalfield[D]. Huainan: Anhui University of Technology, 2016.
|
| [35] |
严智操. 微量元素在两淮矿区的环境地球化学及其在光催化中的应用研究[D]. 合肥: 中国科学技术大学, 2014.
YAN Zhicao. Environmental geochemistry of trace elements in Lianghuai coalfield and its application in photocatalysis[D]. Hefei: China University of Science and Technology, 2014.
|
| [36] |
李 晖, 郑刘根, 刘桂建. 淮南张集矿区煤中微量元素的含量分布特征分析[J]. 岩石矿物学杂志, 2011, 30(4): 696−700.
LI Hui, ZHENG Liugen, LIU Guijian. Analysis on the content distribution characteristics of trace elements in coal of Huainan Zhangji coal mine [J]. Journal of Rock Mineralogy, 2011, 30 (04): 696−700.
|
| [37] |
葛 涛. 淮南煤田煤中有害元素特征研究[D]. 淮南: 安徽理工大学, 2009.
GE Tao. Study on characteristics of hazardous elements in coal of Huainan Coalfield [D]. Huainan: Anhui University of Technology 2009.
|
| [38] |
FU Biao,LIU Guijian,LIU Yuan,et al. Coal quality characterization and its relationship with Geological process of the Early Permian Huainan coal deposits, southern North China[J]. Journal of Geochemical Exploration,2016,166:33−44.
|
| [39] |
CHEN Jian,LIU Guijiang,LI Hui,et al. Mineralogical and geochemical responses of coal to igneous intrusion in the Pansan Coal Mine of the Huainan coalfield, Anhui, China[J]. International Journal of Coal Geology,2014,124:11−35.
|
| [40] |
SUN Ruiyu,LIU Guijian,ZHENG Liugeng,et al. Characteristics of coal quality and their relationship with coal-forming environment: A case study from the Zhuji exploration area, Huainan coalfield, Anhui, China[J]. Energy,2010,35(1):423−435. doi: 10.1016/j.energy.2009.10.009
|
| [41] |
SUN Ruiyu, LIU Guijian, ZHENG Liugeng, et al. Geochemistry of trace elements in coals from the Zhuji Mine, Huainan Coalfield, Anhui, China [J]. International Journal of Coal Geology, 2010, 81(2): 81−96.
|
| [42] |
ZHOU Chuncai,LIUGuijian,WU Dun,et al. Mobility behavior and environmental implications of trace elements associated with coal gangue: A case study at the Huainan Coalfield in China[J]. Chemosphere,2014,95:193−199. doi: 10.1016/j.chemosphere.2013.08.065
|
| [43] |
YANG Mei, LIU Guijian, SUN Ruoyu, et al. Characterization of intrusive rocks and REE geochemistry of coals from the Zhuji Coal Mine, Huainan Coalfield, Anhui, China [J]. International Journal of Coal Geology, 2012, 94: 283−295.
|
| [44] |
YAN Zhicao,LIU Guijian,SUN Ruoyu,et al. Geochemistry of trace elements in coals from the Huainan Coalfield, Anhui, China[J]. Geochemical Journal,2014,48:331−344. doi: 10.2343/geochemj.2.0309
|
| [45] |
DING Dianshi, LIU Guijian, FU Biao, et al. Characteristics of the coal quality and elemental geochemistry in Permian coals from the Xinjier mine in the Huainan Coalfield, north China: Influence of terrigenous inputs [J]. Journal of Geochemical Exploration, 2018, 186: 50−60.
|
| [46] |
DJ Swaine,Goodarzi(eds). Environmental aspects of trace elements of coal[J]. Dordrecht: Kluwer Academic Publishers,1995:24−50.
|
| [47] |
MP Ketris, YE Yudovich. Estimations of clarkes for carbonaceous biolithes: world averages for trace element contents in black shales and coals [J]. International Journal of Coal Geology, 2009, 78(2): 135−148.
|
| [48] |
刘桂建,彭子成,杨萍玥,等. 煤中微量元素富集的主要因素分析[J]. 煤田地质与勘探,2001,30(4):1−4.
LIU Guijian,PENG Zicheng,YANG Pingyue,et al. Analysis on main factors of trace element enrichment in coal[J]. Coalfield Geology and Exploration,2001,30(4):1−4.
|
| [49] |
魏振岱. 安徽省煤炭资源赋存规律与找煤预测[D]. 北京: 地质出版社, 2012.
WEI Zhengdai. Occurrence regularity of coal resources in Anhui Province and prediction of coalexploration[D]. Beijing: Geological Publishing House, 2012.
|
| [50] |
王运泉, 任德贻, 王隆国. 煤中微量元素的赋存状态[J]. 煤田地质与勘探, 1995, 24(2): 9−13.
WANG Yunquan, REN Deyi, WANG Longguo. Modes of occurrence of trace elements in coal[J]. Coalfield Geology and Exploration, 1995, 24 (2): 9−13.
|
| [51] |
唐书恒, 秦 勇, 姜尧发, 等. 中国洁净煤地质研究[M]. 北京: 地质出版社, 2006.
TANG Shuheng, QIN Yong, JIANG Yaofa, et al. Geological research on clean coal in China[M]. Beijing: Geological Publishing House, 2006.
|
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