Occurrence characteristics of Sr in coal from Tashan Coal Mine in Datong,Shanxi Province

MEN Changyu; SONG Xiaoxia; MA Hongtao; LI Wei; YAN Jiwei; GAO Wenxuan

doi:10.13199/j.cnki.cst.2023-0022

Volume 52 Issue S1

Aug. 2024

Turn off MathJax

Article Contents

Abstract

References

COAL SCIENCE AND TECHNOLOGY > 2024 > 52(S1): 164-173. > DOI: 10.13199/j.cnki.cst.2023-0022

MEN Changyu，SONG Xiaoxia，MA Hongtao，et al. Occurrence characteristics of Sr in coal from Tashan Coal Mine in Datong,Shanxi Province[J]. Coal Science and Technology，2024，52（S1）：164−173. DOI: 10.13199/j.cnki.cst.2023-0022

Citation:

PDF (3605 KB)

Occurrence characteristics of Sr in coal from Tashan Coal Mine in Datong,Shanxi Province

MEN Changyu^1,,
SONG Xiaoxia^{1, 2, ,},
MA Hongtao³,
LI Wei^{4, 5},
YAN Jiwei^{1, 6},
GAO Wenxuan¹

1.
Department of Geosciences and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
2.
Shanxi Key Laboratory of Coal and Coal-measure Gas Geology, Taiyuan 030024, China
3.
University of Alberta, Department of Chemical and Materials Engineering, Edmonton T6G 1H9, Alberta
4.
Institute of Unconventional Oil & Gas, Northeast Petroleum University, Daqing 163318, China
5.
Key Laboratory of continental shale hydrocarbon accumulation and efficient development, Ministry of Education, Daqing 163318, China
6.
Key Laboratory of In-Situ Properties-Modified Mining of Ministry of Education, Taiyuan 030024, China

Funds:

National Natural Science Foundation of China (41902176)

More Information

Received Date: February 04, 2023
Available Online: May 19, 2024

Graphical Abstract

Abstract

Abstract

Datong Coalfield was intruded by igneous intrusions in both the Indosinian (Late Permian to the end of the Triassic) and the Yanshan (Late Jurassic to the Early Cretaceous) periods, which caused contact metamorphism of the coal seam. Previous studies have shown that Sr is significantly enriched in coal from the 5222 tunnel of the Tashan coal mine. The maximum concentration of Sr in thermally-altered and unaffected coal is 3067 μg/g and 2729 μg/g respectively, and the average concentration of Sr is 1165 μg/g, which is 10.6times of the world average level in hard coal. However, the modes of occurrence of Sr in the Tashan coal still remain unclear. Samples in the 5222 tunnel including coal and intrusive rock were systematically collected. Inductively coupled plasma mass spectrometry (ICP-MS) and X-ray fluorescence spectrometry (XRF) were applied to elucidate Sr concentration variations in the sample; correlation analysis, scanning electron microscope with energy spectrum (SEM-EDS), and sequential chemical extraction procedure (SCEP) were carried out to reveal the occurrence modes of Sr, as well as the characteristics of Sr-bearing minerals. The results demonstrated that Sr exhibits a strong correlation with P₂O₅ in coal; Sr mainly occurs in phosphate (apatite) and clay minerals that are intimately associated; apatite was distinguished as fluorapatite in the shape of hexagonal columns and hydroxyapatite in the shape of fine scattered particles embedded in the clay minerals.
- Tashan coal mine,
- coal,
- Sr,
- apatite,
- modes of occurrence

FullText(HTML)

References (28)

References

[1]	任德贻,赵峰华,代世峰,等. 煤的微量元素地球化学[M]. 北京:科学出版社,2006:61−335. REN Deyi,ZHAO Fenghua,DAI Shifeng,et al. Geochemistry of trace elements in coal[M]. Beijing:Science Press,2006:61−335.
[2]	代世峰,任徳贻,周义平,等. 煤型稀有金属矿床:成因类型、赋存状态和利用评价[J]. 煤炭学报,2014,39(8):1707−1715. DAI Shifeng,REN Deyi,ZHOU Yiping,et al. Coal-hosted rare metal deposits:Genetic types,modes of occurrence,and utilization evaluation[J]. Journal of China Coal Society,2014,39(8):1707−1715.
[3]	魏强,代世峰. 中国煤型锗矿床中的关键金属和有害元素:赋存特征与富集成因[J]. 煤炭学报,2020,45(1):296−303. WEI Qiang,DAI Shifeng. Critical metals and hazardous elements in the coal-hosted germanium ore deposits of China:Occurrence characteristics and enrichment causes[J]. Journal of China Coal Society,2020,45(1):296−303.
[4]	邹建华,王冰峰,王慧,等. 重庆芦塘矿晚二叠世煤中微量元素和稀土元素的地球化学特征[J]. 煤炭学报,2022,47(8):3117−3127. ZOU Jianhua,WANG Bingfeng,WANG Hui,et al. Geochemical characteristics of trace and rare earth elements in the late Permian coals from the Lutang Mine,Chongqing[J]. Journal of China Coal Society,2022,47(8):3117−3127.
[5]	BARUAH M K,KOTOKY P,BORAH G C. Distribution and nature of organic/mineral bound elements in Assam coals,India[J]. Fuel,2003,82(14):1783−1791. doi: 10.1016/S0016-2361(03)00107-8
[6]	WARD C R. Analysis,origin and significance of mineral matter in coal:An updated review[J]. International Journal of Coal Geology,2016,165:1−27. doi: 10.1016/j.coal.2016.07.014
[7]	DAI S,GRAHAM I T,WARD C R. A review of anomalous rare earth elements and yttrium in coal[J]. International Journal of Coal Geology,2016,159:82−95. doi: 10.1016/j.coal.2016.04.005
[8]	DAI S,REN D,TANG Y,et al. Concentration and distribution of elements in Late Permian coals from western Guizhou Province,China[J]. International Journal of Coal Geology,2005,61:19−137.
[9]	DAI S,LI D,CHOU C,et al. Mineralogy and geochemistry of boehmite-rich coals:New insights from the Haerwusu Surface Mine,Jungar Coalfield,Inner Mongolia,China[J]. International Journal of Coal Geology,2008,74:185−202. doi: 10.1016/j.coal.2008.01.001
[10]	ESKENAZY G M. Trace elements geochemistry of the Dobrudza coal basin,Bulgaria[J]. International Journal of Coal Geology,2009,78(3):192−200. doi: 10.1016/j.coal.2009.01.005
[11]	IORDANIDIS A. Geochemical aspects of Amynteon lignites,Northern Greece[J]. Fuel,2002,81:1723−1732. doi: 10.1016/S0016-2361(02)00071-6
[12]	WARD C R. Analysis and significance of mineral matter in coal seams[J]. International Journal of Coal Geology,2002,50(1/2/3/4):135−168. doi: 10.1016/S0166-5162(02)00117-9
[13]	DAI S,HOWER J C,WARD C R,et al. Elements and phosphorus minerals in the middle Jurassic inertinite-rich coals of the Muli Coalfield on the Tibetan Plateau[J]. International Journal of Coal Geology,2015,144/145:23−47.
[14]	SPIRO B F,LIU J,DAI S,et al. Marine derived ⁸⁷Sr/⁸⁶Sr in coal,a new key to geochronology and palaeoenvironment:Elucidation of the India-Eurasia and China-Indochina collisions in Yunnan,China[J]. International Journal of Coal Geology,2019,215:103304. doi: 10.1016/j.coal.2019.103304
[15]	FINKELMAN R B,PALMER C A,WANG P. Quantification of the modes of occurrence of 42 elements in coal[J]. International Journal of Coal Geology,2017,185:138−160.
[16]	SHAVER S A,HOWER J C,EBLE C F,et al. Trace element geochemistry and surface water chemistry of the Bon Air coal,Franklin County,Cumberland Plateau,southeast Tennessee[J]. International Journal of Coal Geology,2006,67:47−78. doi: 10.1016/j.coal.2005.08.005
[17]	QI H,HU R,ZHANG Q. Concentration and distribution of trace elements in lignite from the Shengli Coalfield,Inner Mongolia,China:implications on origin of the associated Wulantuga germanium deposit[J]. International Journal of Coal Geology,2007,71(2/3):129−152.
[18]	CHEN J,LIU G,LI H,et al. Mineralogical and geochemical responses of coal to igneous intrusion in the Pansan Coal Mine of the Huainan coalfield,Anhui,China[J]. International Journal of Coal Geology,2014,124:11−35. doi: 10.1016/j.coal.2013.12.018
[19]	魏迎春,华芳辉,何文博,等. 峰峰矿区2号煤中微量元素富集特征差异性研究[J]. 煤炭学报,2020,45(4):1473−1487. WEI Yingchun,HUA Fanghui,HE Wenbo,et al. Difference of trace elements characteristics of No. 2 coal in Fengfeng mining area[J]. Journal of China Coal Society,2020,45(4):1473−1487.
[20]	DAI S,REN D. Effects of magmatic intrusion on mineralogy and geochemistry of coals from the Fengfeng-Handan Coalfield,Hebei,China[J]. Energy & Fuels,2007,21:1663−1673.
[21]	SONG X,MA H,SAALIDONG B M,et al. Petrography,Mineralogy,and geochemistry of thermally altered coal in the Tashan Coal Mine,Datong Coalfield,China[J]. Minerals,2021,11(9):1024−1024. doi: 10.3390/min11091024
[22]	马宏涛. 大同煤田火成岩的侵入特征及接触变质煤的煤岩学研究[D]. 太原:太原理工大学,2020:15−23. MA Hongtao. Characteristic of igneous intrusions,and petrography of contact metamorphosed coal in the Datong Coalfield[D]. Taiyuan:Taiyuan University of Technology,2020:15−23.
[23]	申伟刚. 沁水煤田高铝煤的地球化学特征[D]. 邯郸:河北工程大学,2019:28−29. SHEN Weigang. Geochemical characteristics of high alumina coal in Qinshui coalfield[D]. Handan:Hebei University of Engineering,2019:28−29.
[24]	王佳美. 山西高阳石炭–二叠纪含煤岩系中伴生元素富集分异机理[D]. 石家庄:河北地质大学,2021:62−63. WANG Jiamei. Enrichment and differentiation mechanism of associated elements in permo-carboniferous coal in Gaoyang Mine,Shanxi Province[D]. Shijiazhuang:Hebei GEO University,2021:62−63.
[25]	康健. 乌海石炭二叠纪煤中元素的分布规律和矿物质富集机理[D]. 北京:中国矿业大学(北京),2015:59−61. KANG Jian. Distribution of elements and enrichment mechanism of mineral matter in the Wuhai C-P coals[D]. Beijing:China University of Mining & Technology-Beijing,2015:59−61.
[26]	杜勇,朱园园,宋虎跃,等. 微量磷灰石中磷酸根氧同位素分析方法[J]. 地球科学,2019,44(2):456−462. DU Yong,ZHU Yuanyuan,SONG Huyue,et al. Analytical method for δ¹⁸O of phosphate in trace apatite[J]. Earth Science,2019,44(2):456−462.
[27]	VENNEMANN T W,FRICKE H C,BLAKE R E,et al. Oxygen isotope analysis of phosphates a comparison of techniques for analysis of Ag₃PO₄[J]. Chemical Geology,2002,185(3/4):321−336.
[28]	SUN S,MCDONOUGH W F. Chemical and isotopic systematics of oceanic basalts:implications for mantle composition and processes[J]. Geological Society London Special Publications,1989,42(1):13−45.

Cited By

Get Citation

PDF

XML

Article views (26) PDF downloads (8)

Occurrence characteristics of Sr in coal from Tashan Coal Mine in Datong,Shanxi Province

Abstract

References

Catalog

Related

Occurrence characteristics of Sr in coal from Tashan Coal Mine in Datong,Shanxi Province

Abstract

References

Catalog

Related

Export File

Citation

Format

Content