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不同粒度半焦的低温干燥特性研究

Study on drying characteristics with low temperature of different particle size semi-coke

  • 摘要: 为了降低半焦的运输成本以及提高半焦的燃烧效率,通过扫描电镜、N2吸附、X射线光电子能谱分析对神木半焦进行表面结构性质研究,并通过鼓风热力干燥的方式对不同粒度的半焦进行干燥脱水试验研究。结果表明:半焦的孔隙发达,但其含氧官能团较原煤有明显减少,其水分大多以物理吸附的方式存在于孔隙中,鼓风干燥可使水分充分蒸发;干燥温度越高,同一种粒度半焦的水分损失速率越快,干燥时间越短;当干燥温度小于200 ℃时,水分损失的快慢依次为焦粉>小粒>中粒;当干燥温度为250 ℃时,水分损失的快慢依次为焦粉>中粒>小粒;当温度大于300 ℃时,3种粒度的半焦水分损失率相接近,干燥总时间为50 min。因此,干燥温度宜采用200~250 ℃,干燥后的半焦会有1.0%~1.6%的水分吸湿,全水分控制在2.0%左右。

     

    Abstract: In order to reduce the transportation cost of the semi-coke and improve the combustion efficiency,scanning electron microscopy(SEM),N2 adsorption-desorption and X-ray photoelectron spectroscopy(XPS)analysis were used to study the surface structure of Shenmu semi-coke,and the drying and dehydration on different sizes of semi-coke was studied by air-blast drying.The results show that the pores of semi-coke are developed,but the oxygen functional groups of the semi-coke are obviously reduced compared with the raw coal,and the moisture of the semi-coke is mostly physically adsorbed in the pores,and the moisture can be evaporated fully by air-blast drying.What’s more,the higher the drying temperature,the faster the water loss rate of the same particle size semi-coke,and the shorter the drying time.When the drying temperature is less than 200 ℃,the dehydration rate is fine grain > small-sized grain > medium grain;when drying temperature is 250 ℃,the moisture loss is in the order of fine grain>middle grain>small grain,and when the drying temperature is more than 300 ℃,the three-grained semi-coke water loss rate is close to each other,and the total drying time is 50 min.Therefore,the drying temperature should be 200~250 ℃.After drying,the dried semi-coke will have 1.0%~1.6% moisture absorption,the whole moisture content will be controlled at about 2.0%.

     

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